Chemical Strengthening of Glass

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Chemical and Molecular Sciences".

Deadline for manuscript submissions: closed (28 February 2019) | Viewed by 2842

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Guest Editor
Department of Industrial Engineering, University of Trento, via Sommarive, 9 - I-38123 Trento, Italy
Interests: glass science and technology; ceramics processing and engineering; mechanical properties of materials; recovery and re-use of inorganic residues and materials
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Special Issue Information

Dear Colleagues,

Ion exchange treatments have been used since the pioneering works by Kistler, Acloque, and Tochon in the early sixties on the reinforcement of silicate glasses.  The process, generally defined as chemical strengthening or tempering, is based on the substitution of small alkaline ions in a glass structure (Li and/or Na) with larger monovalent cations (typically K) from a molten salt in which the glass is immersed; the treatment carried out at temperatures below the strain point is responsible for the generation of compressive stresses in the surface layers associated with a kind of “stuffing” effect, whose intensity and extension depend fundamentally on glass composition, processing temperature, and time.  Over the years, chemical strengthening has been applied to many industrial glass components like cockpit windows for aircrafts, high speed train windshields, high-end ophthalmic glasses, glasses for copy machines, hard disks, and autoinjector cartridges; more recently, this process has become fundamental for most display windows in electronic devices like cellular phones or tablets.  Additional applications are now on the market such as architectural glazing, solar energy conversion collectors, pharmaceutical containers, and car windshields.

Despite these broad industrial applications, several scientific aspects are still not completely clear, such as the glass structure modification during the ion exchange process or the influence of glass and salt composition on the strengthening process.  In addition, new treatments that are alternatives to the traditional salt bath immersion need to be developed to reduce processing times and costs. Moreover, innovative techniques suitable for the rapid and easy-to-use characterization of the strengthening effect are often required to guarantee optimal and controlled mechanical performances of the produced glass components.

The Special Issue of the Applied Sciences journal titled “Chemical Strengthening of Glass” aims to collect recent advances in the understanding of the ion exchange process, in the developments of new processing techniques, in the innovative applications of chemical strengthening to glass components, and in the development on new characterization techniques.

Prof. Dr. Vincenzo M. Sglavo
Guest Editor

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Keywords

  • glass
  • chemical strengthening
  • chemical tempering
  • ion exchange
  • residual stress
  • strength

Published Papers (1 paper)

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Research

11 pages, 3167 KiB  
Article
Stresses Produced in the BK7 Glass by the K+–Na+ Ion Exchange: Real-Time Process Control Method
by Roman Rogoziński
Appl. Sci. 2019, 9(12), 2548; https://doi.org/10.3390/app9122548 - 21 Jun 2019
Cited by 4 | Viewed by 2333
Abstract
The paper presents the results of tests on stresses produced by the K+↔Na+ ion exchange method in BK7 glass. Diffusion ion exchange processes were carried out in glass plates with a surface area of a few cm2. The [...] Read more.
The paper presents the results of tests on stresses produced by the K+↔Na+ ion exchange method in BK7 glass. Diffusion ion exchange processes were carried out in glass plates with a surface area of a few cm2. The duration of these processes ranged from several hours to several hundred hours; process temperatures from 370 to 402 degree Celsius were used. The area of the glass in which the ion exchange took place shows refractive changes which are also accompanied by stresses. The planar waveguides produced in this way were tested by optical methods (for wavelength λ = 677 nm) and the refractive index profiles for the Transverse Electric (TE) and Transverse Magnetic (TM) polarization states were determined. On the basis of elasto-optic constants, the resulting stresses were determined. The temperature characteristics of diffusion coefficients of exchanged ions were also determined. Based on them a numerical simulation of real-time diffusion processes was possible, which allowed to predict the stresses arising in the glass. A good agreement between these predictions and the results of measurements was obtained. Full article
(This article belongs to the Special Issue Chemical Strengthening of Glass)
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