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Nanomaterials 2016, 6(11), 198; doi:10.3390/nano6110198

Tuning the Emission Energy of Chemically Doped Graphene Quantum Dots

1
Department of Physics, The Islamia University of Bahawalpur, 63100 Bahawalpur, Pakistan
2
Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping, Sweden
*
Authors to whom correspondence should be addressed.
Academic Editor: Ho Won Jang
Received: 22 August 2016 / Revised: 24 October 2016 / Accepted: 28 October 2016 / Published: 3 November 2016
(This article belongs to the Special Issue 2D Nanomaterials: Graphene and Beyond Graphene)
View Full-Text   |   Download PDF [3322 KB, uploaded 3 November 2016]   |  

Abstract

Tuning the emission energy of graphene quantum dots (GQDs) and understanding the reason of tunability is essential for the GOD function in optoelectronic devices. Besides material-based challenges, the way to realize chemical doping and band gap tuning also pose a serious challenge. In this study, we tuned the emission energy of GQDs by substitutional doping using chlorine, nitrogen, boron, sodium, and potassium dopants in solution form. Photoluminescence data obtained from (Cl- and N-doped) GQDs and (B-, Na-, and K-doped) GQDs, respectively exhibited red- and blue-shift with respect to the photoluminescence of the undoped GQDs. X-ray photoemission spectroscopy (XPS) revealed that oxygen functional groups were attached to GQDs. We qualitatively correlate red-shift of the photoluminescence with the oxygen functional groups using literature references which demonstrates that more oxygen containing groups leads to the formation of more defect states and is the reason of observed red-shift of luminescence in GQDs. Further on, time resolved photoluminescence measurements of Cl- and N-GQDs demonstrated that Cl substitution in GQDs has effective role in radiative transition whereas in N-GQDs leads to photoluminescence (PL) quenching with non-radiative transition to ground state. Presumably oxidation or reduction processes cause a change of effective size and the bandgap. View Full-Text
Keywords: graphene quantum dots; emission energy; XPS; photoluminescence; time resolved photoluminescence graphene quantum dots; emission energy; XPS; photoluminescence; time resolved photoluminescence
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Noor-Ul-Ain; Eriksson, M.O.; Schmidt, S.; Asghar, M.; Lin, P.-C.; Holtz, P.O.; Syväjärvi, M.; Yazdi, G.R. Tuning the Emission Energy of Chemically Doped Graphene Quantum Dots. Nanomaterials 2016, 6, 198.

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