Next Article in Journal
Evaluation of Cholinesterase Activities During in Vivo Intoxication Using an Electrochemical Sensor Strip – Correlation With Intoxication Symptoms
Next Article in Special Issue
Recent Findings Concerning PAMAM Dendrimer Conjugates with Cyclodextrins as Carriers of DNA and RNA
Previous Article in Journal
Monitoring Animal Behaviour and Environmental Interactions Using Wireless Sensor Networks, GPS Collars and Satellite Remote Sensing
Previous Article in Special Issue
Vibration and Fluorescence Spectra of Porphyrin- CoredBis(methylol)-propionic Acid Dendrimers
Sensors 2009, 9(5), 3604-3626; doi:10.3390/s90503604

Metal Ion Enhanced Charge Transfer in a Terpyridine-bis-Pyrene System

2, 2
1 Molecular Photonics Group, Van’t Hoff Institute for Molecular Sciences, Universiteit Van Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands 2 Physikalisches Institut, Westfälische Wilhelms-Universität Münster, Mendelstrasse 7, D-48149 Münster, Germany
* Author to whom correspondence should be addressed.
Received: 7 April 2009 / Revised: 8 May 2009 / Accepted: 12 May 2009 / Published: 13 May 2009
(This article belongs to the Special Issue Dendritic Sensors: From Dendrimer Molecules to Dendritic Cells)
View Full-Text   |   Download PDF [488 KB, uploaded 21 June 2014]   |  


The synthesis, electrochemical and photophysical properties of a branched molecule 3,5-bis(pyrene-1-yl)-4'-phenyl-2,2':6',2''-terpyridine are reported. Spectroscopy in different solvents reveals that an optical electron transfer from the pyrene donor to the terpyridyl electron acceptor can occur in polar media, as the system displays both charge transfer (CT) absorption and CT emission. Furthermore, the study of the zinc complex as well as the bis-protonated form shows an enhancement of the electron transfer character of the system, by an increase of the acceptor strength. This is accompanied by a large increase of the non-radiative processes. With sub-nanosecond transient absorption spectroscopy, the CT state, consisting of the pyrene radical cation and the terpyridine radical anion, has been detected. At room temperature, the study of the nanosecond transient absorption spectra reveals the formation of a low-lying triplet excited state that we attribute to the pyrene moiety through which the CT state decays. At 77K, the absence of the terpyridine triplet emission also suggests the population of a low-lying triplet state of the pyrene unit.
Keywords: branched molecules; spectroscopy; ion complexation; excited state absorption; emission; molecular polarity sensor branched molecules; spectroscopy; ion complexation; excited state absorption; emission; molecular polarity sensor
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote |
MDPI and ACS Style

D’Aléo, A.; Cecchetto, E.; De Cola, L.; Williams, R.M. Metal Ion Enhanced Charge Transfer in a Terpyridine-bis-Pyrene System. Sensors 2009, 9, 3604-3626.

View more citation formats

Related Articles

Article Metrics

For more information on the journal, click here


[Return to top]
Sensors EISSN 1424-8220 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert