Sensors 2002, 2(1), 11-22; doi:10.3390/s20100011
Article

A (Bio-)Chemical Field-Effect Sensor with Macroporous Si as Substrate Material and a SiO2 / LPCVD-Si3N4 Double Layer as pH Transducer

1 University of Applied Sciences Aachen, Ginsterweg 1, 52428 Jülich, Germany 2 Institute of Thin Films and Interfaces, Research Centre Jülich GmbH, 52425 Jülich, Germany
* Author to whom correspondence should be addressed.
Received: 29 November 2001; Accepted: 19 December 2001 / Published: 15 January 2002
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Abstract: Macroporous silicon has been etched from n-type Si, using a vertical etching cell where no rear side contact on the silicon wafer is necessary. The resulting macropores have been characterised by means of Scanning Electron Microscopy (SEM). After etching, SiO2 was thermally grown on the top of the porous silicon as an insulating layer and Si3N4 was deposited by means of Low Pressure Chemical Vapour Deposition (LPCVD) as transducer material to fabricate a capacitive pH sensor. In order to prepare porous biosensors, the enzyme penicillinase has been additionally immobilised inside the porous structure. Electrochemical measurements of the pH sensor and the biosensor with an Electrolyte/Insulator/Semiconductor (EIS) structure have been performed in the Capacitance/Voltage (C/V) and Constant capacitance (ConCap) mode.
Keywords: Macroporous silicon; pH sensor; Penicillin biosensor; Thermal oxidation; LPCVD-Si3N4; long-term stability

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MDPI and ACS Style

Schöning, M.J.; Simonis, A.; Ruge, C.; Ecken, H.; Müller-Veggian, M.; Lüth, H. A (Bio-)Chemical Field-Effect Sensor with Macroporous Si as Substrate Material and a SiO2 / LPCVD-Si3N4 Double Layer as pH Transducer. Sensors 2002, 2, 11-22.

AMA Style

Schöning MJ, Simonis A, Ruge C, Ecken H, Müller-Veggian M, Lüth H. A (Bio-)Chemical Field-Effect Sensor with Macroporous Si as Substrate Material and a SiO2 / LPCVD-Si3N4 Double Layer as pH Transducer. Sensors. 2002; 2(1):11-22.

Chicago/Turabian Style

Schöning, Michael J.; Simonis, Anette; Ruge, Christian; Ecken, Holger; Müller-Veggian, Mattea; Lüth, Hans. 2002. "A (Bio-)Chemical Field-Effect Sensor with Macroporous Si as Substrate Material and a SiO2 / LPCVD-Si3N4 Double Layer as pH Transducer." Sensors 2, no. 1: 11-22.

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