Abstract: Nitrogen compounds like urea and melamine are known to be commonly used for milk adulteration resulting in undesired intoxication; a well-known example is the Chinese episode occurred in 2008. The development of a rapid, reliable and economic test is of relevance in order to improve adulterated milk identification. Cyclic voltammetry studies using an Au working electrode were performed on adulterated and non-adulterated milk samples from different independent manufacturers. Voltammetric data and their first derivative were subjected to functional principal component analysis (f-PCA) and correctly classified by the KNN classifier. The adulterated and non-adulterated milk samples showed significant differences. Best results of prediction were obtained with first derivative data. Detection limits in milk samples adulterated with 1% of its total nitrogen derived from melamine or urea were as low as 85.0 mg·L−1 and 121.4 mg·L−1, respectively. We present this method as a fast and robust screening method for milk adulteration analysis and prevention of food intoxication.
Keywords: f-PCA; KNN; milk adulteration; voltammetry; rapid screening methods
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Hilding-Ohlsson, A.; Fauerbach, J.A.; Sacco, N.J.; Bonetto, M.C.; Cortón, E. Voltamperometric Discrimination of Urea and Melamine Adulterated Skimmed Milk Powder. Sensors 2012, 12, 12220-12234.
Hilding-Ohlsson A, Fauerbach JA, Sacco NJ, Bonetto MC, Cortón E. Voltamperometric Discrimination of Urea and Melamine Adulterated Skimmed Milk Powder. Sensors. 2012; 12(9):12220-12234.
Hilding-Ohlsson, Astrid; Fauerbach, Jonathan A.; Sacco, Natalia J.; Bonetto, M. Celina; Cortón, Eduardo. 2012. "Voltamperometric Discrimination of Urea and Melamine Adulterated Skimmed Milk Powder." Sensors 12, no. 9: 12220-12234.