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A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations
Dicle University, Faculty of Education, Department of Chemistry, 21280, Diyarbakir, Turkey
Balikesir University, Faculty of Science and Art, Department of Chemistry, 10145, Balikesir, Turkey
* Author to whom correspondence should be addressed.
Received: 30 July 2007; in revised form: 20 August 2007 / Accepted: 27 August 2007 / Published: 4 September 2007
Abstract: The constants of the extraction equilibrium and the distribution fordichloromethane as an organic solvent having low dielectric constant of metal cations withchiral Schiff bases, benzaldehydene-(S)-2-amino-3-phenylpropanol (I), o- benzaldehydene-(S)-2-hydroxybenzaldehydene-(S)-2-amino-3-phenyl-propanol (II),amino-3-methylbutanol (III) with anionic dyes [4-(2-pyridylazo)-resorcinol mono sodiummonohydrate (NaPar), sodium picrat (NaPic) and potassium picrat (KPic)] and some heavymetal chlorides were determined at 25 oC. All the ligands have given strongestcomplexation for NaPar. In contrast, similar behaviour for both alkali metal picrates is notapparent in the complexation of corresponding ligands.
Keywords: Chiral Schiff bases; Extraction; Alkali metal picrates; Anionic dyes; Spectroscopy.
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Topal, G.; Tümerdem, R.; Basaran, I.; Gümüş, A.; Cakir, U. A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations. Int. J. Mol. Sci. 2007, 8, 933-942.
Topal G, Tümerdem R, Basaran I, Gümüş A, Cakir U. A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations. International Journal of Molecular Sciences. 2007; 8(9):933-942.
Topal, Giray; Tümerdem, Recep; Basaran, Ismet; Gümüş, Arzu; Cakir, Umit. 2007. "A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations." Int. J. Mol. Sci. 8, no. 9: 933-942.