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Int. J. Mol. Sci. 2007, 8(9), 943-949; doi:10.3390/i8090943

Isotopic Effect on the Kinetics of the Belousov-Zhabotinsky Reaction

1
Department of Physical Chemistry "F. Accascina", University of Palermo, Viale delle Scienze Pad. 17, Palermo, Italy
2
Department of Chemistry, University of Sassari, Via Vienna 2, Sassari, Italy
3
Department of Chemical and Biosystems Science, University of Siena, Via Aldo Moro 3, Siena, Italy
4
Department of Chemical and Biosystems Science, University of Siena, Via della Diana 2/a, Siena, Italy
*
Author to whom correspondence should be addressed.
Received: 28 June 2007 / Revised: 7 August 2007 / Accepted: 27 August 2007 / Published: 4 September 2007
(This article belongs to the Section Physical Chemistry, Theoretical and Computational Chemistry)
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Abstract

In this work we present results about the deuterium isotope effect on the globalkinetics of a Belousov-Zhabotinsky reaction in batch conditions. A nonlinear dependenceof the Induction Period upon the percentage of deuterated reactants was found. The isotopiceffect on the bromination reaction of malonic acid was evaluated. View Full-Text
Keywords: Belousov-Zhabotinsky reaction; Isotopic effect; Induction Period; Enolization; Bromination reaction. Belousov-Zhabotinsky reaction; Isotopic effect; Induction Period; Enolization; Bromination reaction.
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Rossi, F.; Rustici, M.; Rossi, C.; Tiezzi, E. Isotopic Effect on the Kinetics of the Belousov-Zhabotinsky Reaction. Int. J. Mol. Sci. 2007, 8, 943-949.

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