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Int. J. Mol. Sci. 2010, 11(5), 1973-1990; doi:10.3390/ijms11051973

Article

The Solubility Parameters of Ionic Liquids

Andrzej Marciniak

Department of Physical Chemistry, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland

Received: 1 March 2010; in revised form: 21 April 2010 / Accepted: 22 April 2010 / Published: 27 April 2010

(This article belongs to the Special Issue Advances in Green Chemistry and Sustainable Chemistry)

Download PDF Full-Text [353 KB, uploaded 27 April 2010 16:04 CEST]

Abstract: The Hildebrand’s solubility parameters have been calculated for 18 ionic liquids from the inverse gas chromatography measurements of the activity coefficients at infinite dilution. Retention data were used for the calculation. The solubility parameters are helpful for the prediction of the solubility in the binary solvent mixtures. From the solubility parameters, the standard enthalpies of vaporization of ionic liquids were estimated.

Keywords: ionic liquid; Hildebrand’s solubility parameter; standard enthalpy of vaporization

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