Application of Flow Thermolysis in Organic Synthesis: Easy Access to α,ω-Bis Thienyl- and Bis Pyrrolyl- Alkanes from Methylene Derivatives of Meldrum's Acid

doi:10.3390/51001130

This article is

freely available
re-usable

Molecules 2000, 5(10), 1130-1138; doi:10.3390/51001130

Article

Application of Flow Thermolysis in Organic Synthesis: Easy Access to α,ω-Bis Thienyl- and Bis Pyrrolyl- Alkanes from Methylene Derivatives of Meldrum's Acid

Jean Claude Pommelet^1,* , Fanck Jourdain¹ and Hamid Dhimane²

¹ Laboratoire de Chimie Moléculaire et Thioorganique, UMR 6507, ISMRA, Université de Caen, 6 Bd Maréchal Juin, 14050 Caen, France ² Laboratoire de Chimie des Hétérocycles, UMR 7611, Université Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris 05, France

* Author to whom correspondence should be addressed.

Received: 21 July 2000; in revised form: 26 September 2000 / Accepted: 27 September 2000 / Published: 31 October 2000

Download PDF Full-Text [43 KB, uploaded 9 October 2008 11:50 CEST]

Abstract: Thermal decomposition of Meldrum's acid derivatives and rearrangement of (alkylsulfanyl) or (propargylamino)methylene ketene intermediates leads in one step to bis thienyl- or bis pyrrolyl-alkanes.

Keywords: Thermolysis; organic synthesis; Meldrum's acid; thiophenes; pyrroles

Article Statistics

Click here to load and display the download statistics.

Cite This Article

MDPI and ACS Style

Pommelet, J.C.; Jourdain, F.; Dhimane, H. Application of Flow Thermolysis in Organic Synthesis: Easy Access to α,ω-Bis Thienyl- and Bis Pyrrolyl- Alkanes from Methylene Derivatives of Meldrum's Acid. Molecules 2000, 5, 1130-1138.

AMA Style

Pommelet JC, Jourdain F, Dhimane H. Application of Flow Thermolysis in Organic Synthesis: Easy Access to α,ω-Bis Thienyl- and Bis Pyrrolyl- Alkanes from Methylene Derivatives of Meldrum's Acid. Molecules. 2000; 5(10):1130-1138.

Chicago/Turabian Style

Pommelet, Jean C.; Jourdain, Fanck; Dhimane, Hamid. 2000. "Application of Flow Thermolysis in Organic Synthesis: Easy Access to α,ω-Bis Thienyl- and Bis Pyrrolyl- Alkanes from Methylene Derivatives of Meldrum's Acid." Molecules 5, no. 10: 1130-1138.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert