Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway
AbstractWe have successfully developed a novel cathodic cross-coupling reaction of aryl halides with arenes. Utilization of the cathodic single electron transfer (SET) mechanism for activation of aryl halides enables the cross-coupling reaction to proceed without the need for any transition metal catalysts or single electron donors in a mild condition. The SET from a cathode to an aryl halide initiates a radical chain by giving an anion radical of the aryl halide. The following propagation cycle also consists entirely of anion radical intermediates. View Full-Text
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Qu, Y.; Tateno, H.; Matsumura, Y.; Kashiwagi, T.; Atobe, M. Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway. Molecules 2017, 22, 413.
Qu Y, Tateno H, Matsumura Y, Kashiwagi T, Atobe M. Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway. Molecules. 2017; 22(3):413.Chicago/Turabian Style
Qu, Yang; Tateno, Hiroyuki; Matsumura, Yoshimasa; Kashiwagi, Tsuneo; Atobe, Mahito. 2017. "Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway." Molecules 22, no. 3: 413.
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