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Molecules 2014, 19(9), 13603-13613; doi:10.3390/molecules190913603

Synthesis and Reactivity of New Aminophenolate Complexes of Nickel

1
Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA
2
Department of Chemistry, University of Hawaii, 2545 McCarthy Mall, Honolulu, HI 96822, USA
3
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, 8 Arbuzov str., Kazan 420088, Russia
*
Author to whom correspondence should be addressed.
Received: 8 July 2014 / Revised: 27 August 2014 / Accepted: 28 August 2014 / Published: 2 September 2014
(This article belongs to the Special Issue Practical Applications of Metal Complexes)
View Full-Text   |   Download PDF [1099 KB, uploaded 2 September 2014]   |  

Abstract

New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions. View Full-Text
Keywords: nickel; cross-coupling; coordination chemistry; paramagnetic complexes nickel; cross-coupling; coordination chemistry; paramagnetic complexes
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MDPI and ACS Style

Yu, S.; Wang, H.; Sledziewski, J.E.; Madhira, V.N.; Takahashi, C.G.; Leon, M.K.; Dudkina, Y.B.; Budnikova, Y.H.; Vicic, D.A. Synthesis and Reactivity of New Aminophenolate Complexes of Nickel. Molecules 2014, 19, 13603-13613.

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