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Molecules 2013, 18(12), 15531-15540; doi:10.3390/molecules181215531
Article

Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities

1,* , 1, 1, 2, 2, 1, 1 and 1
Received: 4 November 2013 / Revised: 3 December 2013 / Accepted: 11 December 2013 / Published: 13 December 2013
(This article belongs to the Special Issue Fluorine Chemistry)
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Abstract

The reaction of 1,1-bis(triflyl)ethylene generated in situ with enolizable carbonyls yielded δ-oxo-1,1-bis(triflyl)alkane derivatives. Their acidities in both the gas and solution phases were determined.
Keywords: carbon acid; triflyl group; gas phase acidity; pKa carbon acid; triflyl group; gas phase acidity; pKa
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Yanai, H.; Fujita, M.; Takahashi, A.; Zhang, M.; Mishima, M.; Kotani, A.; Matsumoto, T.; Taguchi, T. Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities. Molecules 2013, 18, 15531-15540.

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