Next Article in Journal
Stereocontrolled Synthesis and Functionalization of Cyclobutanes and Cyclobutanones
Next Article in Special Issue
Crystal Structures and Antifungal Activities of Fluorine-Containing Thioureido Complexes with Nickel(II)
Previous Article in Journal
Seed Germination-Influencing Bioactive Secondary Metabolites Secreted by the Endophyte Cladosporium cladosporioides LWL5
Previous Article in Special Issue
Automated Solid-Phase Radiofluorination Using Polymer-Supported Phosphazenes
Molecules 2013, 18(12), 15531-15540; doi:10.3390/molecules181215531

Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities

1,* , 1, 1, 2, 2, 1, 1 and 1
Received: 4 November 2013 / Revised: 3 December 2013 / Accepted: 11 December 2013 / Published: 13 December 2013
(This article belongs to the Special Issue Fluorine Chemistry)
Download PDF [300 KB, uploaded 18 June 2014]
Abstract: The reaction of 1,1-bis(triflyl)ethylene generated in situ with enolizable carbonyls yielded δ-oxo-1,1-bis(triflyl)alkane derivatives. Their acidities in both the gas and solution phases were determined.
Keywords: carbon acid; triflyl group; gas phase acidity; pKa carbon acid; triflyl group; gas phase acidity; pKa
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |

MDPI and ACS Style

Yanai, H.; Fujita, M.; Takahashi, A.; Zhang, M.; Mishima, M.; Kotani, A.; Matsumoto, T.; Taguchi, T. Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities. Molecules 2013, 18, 15531-15540.

AMA Style

Yanai H, Fujita M, Takahashi A, Zhang M, Mishima M, Kotani A, Matsumoto T, Taguchi T. Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities. Molecules. 2013; 18(12):15531-15540.

Chicago/Turabian Style

Yanai, Hikaru; Fujita, Masaya; Takahashi, Arata; Zhang, Min; Mishima, Masaaki; Kotani, Akira; Matsumoto, Takashi; Taguchi, Takeo. 2013. "Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities." Molecules 18, no. 12: 15531-15540.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert