Molecules 2011, 16(10), 8209-8227; doi:10.3390/molecules16108209
Article

Gold Nanoparticle-Catalyzed Environmentally Benign Deoxygenation of Epoxides to Alkenes

1 Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan 2 Research Center for Solar Energy Chemistry Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan
* Author to whom correspondence should be addressed.
Received: 5 September 2011; in revised form: 16 September 2011 / Accepted: 21 September 2011 / Published: 28 September 2011
(This article belongs to the Special Issue Gold Catalysts)
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Abstract: We have developed a highly efficient and green catalytic deoxygenation of epoxides to alkenes using gold nanoparticles (NPs) supported on hydrotalcite [HT: Mg6Al2CO3(OH)16] (Au/HT) with alcohols, CO/H2O or H2 as the reducing reagent. Various epoxides were selectively converted to the corresponding alkenes. Among the novel metal NPs on HT, Au/HT was found to exhibit outstanding catalytic activity for the deoxygenation reaction. Moreover, Au/HT can be separated from the reaction mixture and reused with retention of its catalytic activity and selectivity. The high catalytic performance of Au/HT was attributed to the selective formation of Au-hydride species by the cooperative effect between Au NPs and HT.
Keywords: gold nanoparticle; hydrotalcite; deoxygenation; epoxide; alkene

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MDPI and ACS Style

Noujima, A.; Mitsudome, T.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K. Gold Nanoparticle-Catalyzed Environmentally Benign Deoxygenation of Epoxides to Alkenes. Molecules 2011, 16, 8209-8227.

AMA Style

Noujima A, Mitsudome T, Mizugaki T, Jitsukawa K, Kaneda K. Gold Nanoparticle-Catalyzed Environmentally Benign Deoxygenation of Epoxides to Alkenes. Molecules. 2011; 16(10):8209-8227.

Chicago/Turabian Style

Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi. 2011. "Gold Nanoparticle-Catalyzed Environmentally Benign Deoxygenation of Epoxides to Alkenes." Molecules 16, no. 10: 8209-8227.

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