Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins

doi:10.3390/molecules15031487

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Molecules 2010, 15(3), 1487-1500; doi:10.3390/molecules15031487

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Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins

Yasushi Obora * and Yasutaka Ishii *

Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering and High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan

* Authors to whom correspondence should be addressed.

Received: 15 January 2010; in revised form: 2 February 2010 / Accepted: 8 March 2010 / Published: 9 March 2010

(This article belongs to the Special Issue Heck Coupling)

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Abstract: The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)₂/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.

Keywords: direct coupling; oxidative coupling; arenes; molybdovanadophosphoric acid

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MDPI and ACS Style

Obora, Y.; Ishii, Y. Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins. Molecules 2010, 15, 1487-1500.

AMA Style

Obora Y., Ishii Y. Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins. Molecules. 2010; 15(3):1487-1500.

Chicago/Turabian Style

Obora, Yasushi; Ishii, Yasutaka. 2010. "Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins." Molecules 15, no. 3: 1487-1500.

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