Coupling Reactions of α-Bromocarboxylate with Non-Aromatic N-Heterocycles
AbstractThe conditions for the C-N bond forming reaction (C-N coupling reaction) between α-bromocarboxylate and nitrogen-containing non-aromatic heterocyclic rings under heterogeneous copper(I) oxide catalysis are investigated in this paper. All the generated compounds were fully characterized by IR, NMR and MS spectroscopy. Ab initio/DFT calculations of partial charges on nitrogen atoms in all the discussed heterocycles and on C(2) of carboxylate under applied conditions were predicted. These in silico results correlate relatively with the experimental observations. View Full-Text
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Brychtova, K.; Slaba, B.; Placek, L.; Jampilek, J.; Raich, I.; Csollei, J. Coupling Reactions of α-Bromocarboxylate with Non-Aromatic N-Heterocycles. Molecules 2009, 14, 3019-3029.
Brychtova K, Slaba B, Placek L, Jampilek J, Raich I, Csollei J. Coupling Reactions of α-Bromocarboxylate with Non-Aromatic N-Heterocycles. Molecules. 2009; 14(8):3019-3029.Chicago/Turabian Style
Brychtova, Katerina; Slaba, Barbora; Placek, Lukas; Jampilek, Josef; Raich, Ivan; Csollei, Jozef. 2009. "Coupling Reactions of α-Bromocarboxylate with Non-Aromatic N-Heterocycles." Molecules 14, no. 8: 3019-3029.