Finite-element (FE) simulations that go beyond the linear elastic limit of materials can aid the development of polymeric products such as stretch blow molded angioplasty balloons. The FE model requires the input of an appropriate elastoplastic material model. Up to the onset of necking, the identification of the hardening curve is well established. Subsequently, additional information such as the cross-section and the triaxial stress state inside the specimen is required. The present study aims to inversely identify the post-necking hardening behavior of the semi-crystalline polymer polyamide 12 (PA12) at different temperatures. Our approach uses structural FE simulations of a dog-bone tensile specimen in LS-DYNA with mesh sizes of 1 mm and 2 mm, respectively. The FE simulations are coupled with an optimization routine defined in LS-OPT to identify material properties matching the experimental behavior. A Von Mises yield criterion coupled with a user-defined hardening curve (HC) were considered. Up to the beginning of necking, the Hockett–Sherby hardening law achieved the best fit to the experimental HC. To fit the entire HC until fracture, an extension of the Hockett–Sherby law with power-law functions achieved an excellent fit. Comparing the simulation and the experiment, the following coefficient of determination $R^2$ could be achieved: Group I: $R^2$ > 0.9743; Group II: $R^2$ > 0.9653; Group III: $R^2$ > 0.9927. Using an inverse approach, we were able to determine the deformation behavior of PA12 under uniaxial tension for different temperatures and mathematically describe the HC. Full article

We investigate the use of an ionic liquid (IL) as a surfactant in emulsion polymerization (EP) reactions. ILs have been proposed as surfactants for micellar dispersions, emulsions, micro-emulsions and suspensions. Thus, it is important to acquire knowledge of the application of ILs in heterogeneous polymerizations. We selected the amphiphile cationic oligoether IoLiLyte C1EG™ as an IL for this purpose and compared its performance to that of the conventional surfactant dodecyl trimethyl ammonium bromide (DTAB) in the EP of methyl methacrylate and styrene. After we found the proper concentration range of the IL, this amphiphile showed similar polymerization rates to those observed with DTAB for both monomers. The evolution of monomer conversion and the final average diameter of formed polymeric particles were similar for both evaluated surfactants, demonstrating their capability to stabilize the EPs of the investigated monomers. We simulated the evolution of monomer conversion and particle size using a conventional model for emulsion polymerization, which showed good agreement with the experimental data, suggesting that the EP with this IL follows Smith-Ewart kinetics. Full article

Reinforcement steel extensively applied in civil construction is susceptible to corrosion due to the carbonation process in reinforced concrete and chloride ions diffusion. Epoxy-silica-based coatings are a promising option to guarantee the long-term stability of reinforced concrete structures. In this study, the influence of the proportion between the poly (bisphenol-A-co-epichlorhydrin) resin (DGEBA) and the curing agent diethylenetriamine (DETA) on the structural, morphological, and barrier properties of epoxy–silica nanocomposites were evaluated. To simulate different stages of concrete aging, electrochemical impedance spectroscopy (EIS) assays were performed for coated samples in a 3.5 wt.% NaCl solution (pH 7) and in simulated concrete pore solutions (SCPS), which represent the hydration environment in fresh concrete (SCPS2, pH 14) and after carbonation (SCPS1, pH 8). The results showed that coatings with an intermediate DETA to DGEBA ratio of 0.4, presented the best long-term corrosion protection with a low-frequency impedance modulus of up to 3.8 GΩ cm² in NaCl and SCPS1 solutions. Small-angle X-ray scattering and atomic force microscopy analysis revealed that the best performance observed for the intermediate DETA proportion is associated with the presence of larger silica nanodomains, which act as a filler in the cross-linked epoxy matrix, thus favoring the formation of an efficient diffusion barrier. Full article

This paper focused on adding a suitable lubrication effect at the interface between the rubber and mixer chamber wall on reducing the surface wear rate of the mixer chamber wall. In the research process, the contact model between the compound and internal mixer chamber wall was simplified to the pin-on-disc experimental model. The experimental results showed that the friction coefficient and the metal surface wear rate of the mixer chamber were reduced (by approximately 24%) by adding an appropriate amount of antifriction agent in the mixing process, while the comprehensive properties of the compound showed an improvement trend. By analyzing the surface elements of the rubber compound, the MoS₂ with an anti-wear effect on the surface of the rubber compound can form a lubrication mechanism between the rubber, filler, and mixer chamber wall metal. Combined with the result of the comprehensive properties of rubber, which showed that although the appropriate amount of antifriction agent formed a lubrication protection mechanism between the rubber and the inner mixing chamber wall, the mechanism did not affect the friction behavior required for mixing. The study can effectively enhance the effective friction mixing and reduce the wear and power consumption of the mixing chamber caused by excess friction during the mixing process. Full article

Workability and mechanical properties of the seawater sea–sand concrete (SWSSC) were similar to those of ordinary concrete made with freshwater and river sand, which had a wide application in structures. Since the polyoxymethylene (POM) fiber performed the outstanding alkali resistance and durability, POM fibers were added in SWSSC in this study to enhance the mechanical properties. Moreover, the mechanical properties of concrete during the early age have significant effects on the construction phase. The experiment, including 96 test specimens, was conducted to clarify effects of POM fibers on mechanical properties of SWSSC with different ages. The cube compressive, axial compressive, splitting tensile, and flexural tests of NF and POM0.6 SWSSC were conducted. Based on test results, the predictive equations were proposed to quantify relations between concrete age and mechanical properties of NF and POM0.6 SWSSC. Effects of the concrete age on ratios f_tT/f_cT and f_fT/f_cT were investigated and quantified through proposed equations. Failure performances of NF and POM0.6 SWSSC specimens with different ages were analyzed. The microstructure of POM0.6 SWSSC specimens was observed, and the reinforcing mechanism of POM fibers was further explained. Full article

Additive manufacturing (AM) is a rapidly growing technology, referring to a 3D design process by which digital data builds a physical object in layers by depositing the printed material. The AM has evolved in the aviation, automotive, and medical industries. The AM development for fiber-reinforced composites is the point of current interest, with most research focused on using short fibers. However, notwithstanding particular technological complexities, continuous filaments have superior tensile properties compared to short fibers. Therefore, this manuscript develops an adaptive continuous reinforcement approach for AM based on polymeric material extrusion (ME) technology. It combines the raw material production process, including the ability to vary constituents (e.g., filament materials, reinforcement percentage, and recycled plastic replacement ratio), and the reinforcement efficiency analysis regarding the experimentally verified numerical model. The literature review has identified compatible materials for ensuring sustainable and high-performance plastic composites reinforced with continuous fibers. In addition, it identified the applicability of recycled polymers in developing ME processes. Thus, the study includes an experimental program to investigate the mechanical performance of 3D printed samples (polylactic acid, PLA, matrix reinforced with continuous aramid filament) through a tensile test. Recycled polymer replaced 40% of the virgin PLA. The test results do not demonstrate the recycled polymer’s negative effect on the mechanical performance of the printed samples. Moreover, the recycled material reduced the PLA cost by almost twice. However, together with the potential efficiency of the developed adaptive manufacturing technology, the mechanical characteristics of the printed material revealed room for printing technology improvement, including the aligned reinforcement distribution in the printed product and printing parameters’ setup. Full article

Pd-containing precursor has been synthesized from palladium acetate and poly(vinly)silazane (Durazane 1800) in an ice bath under an argon atmosphere. The results of ATR-FTIR and NMR characterizations reveal the chemical reaction between palladium acetate and vinyl groups in poly(vinyl)silazane and the hydrolyzation reaction between –Si–H and –Si–CH=CH₂ groups in poly(vinyl)silazane. The palladium nanoparticles are in situ formed in the synthesized precursors as confirmed by XRD, XPS, and TEM. Pd- and Pd₂Si-containing SiOCN ceramic nanocomposites are obtained by pyrolysis of the synthesized precursors at 700 °C, 900 °C–1100 °C in an argon atmosphere. The pyrolyzed nanocomposites display good catalytic activity towards the dry reforming of methane. The sample pyrolyzed at 700 °C possesses the best catalytic performance, which can be attributed to the in situ formed palladium nanoparticles and high BET surface area of about 233 m² g⁻¹. Full article

Mussels represent about one-third of all aquaculture products sold in the European Union. Theoretically, mussel production should be an environmentally friendly and sustainable activity (0.252 kg CO₂ eq. per 1 kg of mussel produced against over 20 kg CO₂ eq. per 1 kg of beef produced) but the abandoned plastic “socks” on the seabed and along beaches represent a significant environmental problem. The recovery and recycling of those polymer materials represents the proper management of the waste issue due to mussel farming. This study was performed to investigate, for the first time, the roles of the chemical oxidation actions on the detachment (and destruction) of organic matter (biofilm in particular) from the surface of the polypropylene “socks” used in sea farms in order to recover the polymer material and recycle it. In the experiments, oxidation by H₂O₂ and HNO₃ was performed on the studied samples. The effects of the particle size of the fragments, oxidant concentration, agitation time and ultrasound application were determined. FTIR spectra and tensile mechanical properties of the samples after treatment were measured and compared with the virgin polymer material. The biodiversity and structure of the plastic-associated biofilm was also determined before and after the oxidation process. Based on the results of the characterization of the recovered polymer material, a process scheme was designed. The application of the developed process could significantly reduce the environmental risk associated with used mussel socks. The One LIFE (the EU’s funding instrument for the environment and climate action) Project was recently founded based on this research. Full article

In this study, we prepared alginate composite hydrogel beads containing various compositions of biochar produced from pitch pine (Pinus rigida) for the removal of Cu²⁺ and benzene from model pollutant solutions. The properties of the alginate/biochar hydrogel beads were evaluated using scanning electron microscopy, Fourier transform infrared spectroscopy, and Brunauer–Emmet–Teller analyses. Adsorption behavior of alginate/biochar hydrogel beads indicated that the adsorption capacities for Cu²⁺ (28.6–72.7 mg/g) were enhanced with increasing alginate content, whereas the adsorption capacities for benzene (20.0–52.8 mg/g) were improved with increasing biochar content. The alginate/biochar hydrogel beads exhibited similar adsorption capacities for Cu²⁺ and benzene in the concurrent system with Cu²⁺ and benzene compared to those in a single pollutant system. Adsorption kinetics and isotherm studies of the alginate/biochar hydrogel beads followed the pseudo-second-order model (r² = 0.999 for Cu²⁺, and r² = 0.999 for benzene), and Langmuir model (r² = 0.999 for Cu²⁺, and r² = 0.995 for benzene). In addition, alginate/biochar hydrogel beads (containing 1 and 4% biochar) exhibited high reusability (>80%). Therefore, alginate/biochar hydrogel beads can be applied as adsorbents for the removal of multiple pollutants with different properties from wastewater. Full article

The electroless copper plating of textiles, which have been previously printed with a catalyst, is a promising method to selectively metallise them to produce high-reliability e-textiles, sensors and wearable electronics with wide-ranging applications in high-value sectors such as healthcare, sport, and the military. In this study, polyester textiles were ink-jet printed using differing numbers of printing cycles and printing directions with a functionalised copper–silver nanoparticle catalyst, followed by electroless copper plating. The catalyst was characterised using Transmission Electron Microscopy (TEM) and Ultraviolet/Visible (UV/Vis) spectroscopy. The electroless copper coatings were characterised by copper mass gain, visual appearance and electrical resistance in addition to their morphology and the plating coverage of the fibres using Scanning Electron Microscopy (SEM). Stiffness, laundering durability and colour fastness of the textiles were also analysed using a stiffness tester and Launder Ometer, respectively. The results indicated that in order to provide a metallised pattern with the desired conductivity, stiffness and laundering durability for e-textiles, the printing design, printing direction and the number of printing cycles of the catalyst should be carefully optimised considering the textile’s structure. Achieving a highly conductive complete copper coating, together with an almost identical and sufficiently low stiffness on both sides of the textile can be considered as useful indicators to judge the suitability of the process. Full article

Polyethylene terephthalate (PET) is among the most used thermoplastic polymers in large scale manufacturing. Opaque PET is increasingly used in milk bottles to save weight and to bring a glossy white aspect due to TiO₂ nanoparticles. The recyclability of opaque PET is an issue: whereas the recycling channels are well established for transparent PET, the presence of opaque PET in household wastes weakens those channels: opaque bottles cannot be mixed with transparent ones because the resulting blend is not transparent anymore. Many research efforts focus on the possibility to turn opaque PET into resources, as one key to a more circular economy. A recent study has demonstrated the improvement of the mechanical properties of recycled PET through reactive extrusion. In the present work, the lifespan of recycled opaque PET has been evaluated throughout tensile–tensile fatigue loading cycles at various steps of the recycling process: The specimens are obtained from flakes after grinding PET wastes (F-r-OPET), from a subsequent homogenization step (r-OPET-hom) and after reactive extrusion (Rex-r-OPET). Virgin PET is also considered as a comparison. First, tensile tests monitored by digital image correlation have been carried out to obtain the elastic modulus and ultimate tensile stress of each type of PET. The fatigue properties of reactive REx-r-OPET increase, probably associated with the rise of cross-linking and branching rates. The fatigue lifespan increases with the macromolecular weight. The fracture surface analysis of specimens brings new insight regarding the factors governing the fatigue behavior and the damaging mode of recycled PET. TiO₂ nanoparticles act as stress concentrators, contributing to void formation at multiple sites and thus promoting the fracture process. Finally, the fatigue life of REx-r-OPET is comparable to those of virgin PET. Upcycling opaque PET by reactive extrusion may be a relevant new route to absorb some of the growing amounts of PET worldwide. Full article

Complexes of poly(phenylene methylene) (PPM) with silver(I) ions and tricarbonylchromium(0) moieties, respectively, were synthesized. ¹³C NMR spectra indicate interaction of phenylene groups with silver(I) and chromium(0), and peak broadening implies dynamic behavior of the silver(I) complexes, with all phenylene groups temporarily involved in coordination, in contrast to the chromium complexes. About 5–10% of the phenylene groups are coordinated to metal atoms. ¹H NMR and IR spectra, in the case of chromium(0), and the solubility of silver salts in the presence of PPM provide further evidence of coordination. The complexes are soluble in chloroform, but the silver complexes decay in tetrahydrofuran (second-order kinetics were observed in an example). The photoluminescence (fluorescence) of PPM is maintained upon complexation, although coordination of silver(I) seems to favor the so-called blue phase of PPM relative to the green phase by a factor of approximately two in PL spectra. The pronounced absorption of the tricarbonylchromium(0) units interferes with the blue phase, which almost disappears at a concentration of 50 mg/mL in PLE spectra, whereas the emission maximum of the green phase is hardly affected. This leads to a confinement of the emitted wavelength range of PPM. Thus, the perceived optical emission of PPM can be modified by coordinated entities. Full article

Nanocrystals are carrier-free, submicron-sized, colloidal drug delivery systems with particle sizes in the mean nanometer range. Nanocrystals have high bioavailability and fast absorption because of their high dissolution velocity and enhanced adhesiveness to cell membranes. Loxoprofen, a nonsteroidal anti-inflammatory drug belonging to the Biopharmaceutical Classification System (BCS) II drug class, was selected as the model drug. The aim of this study was to formulate nanocrystals of loxoprofen. A total of 12 formulations (F1 to F12) were prepared. An antisolvent technique was used to determine the effects of various stabilizers and processing conditions on the optimization of formulations. The various stabilizers used were hydroxypropyl methylcellulose (0.5%), polyvinylpyrrolidone (0.5%), and sodium lauryl sulfate (0.1%). The various characterizations conducted for this research included stability studies at 25 °C and 4 °C, scanning electron microscopy, transmission electron microscopy (TEM), X-ray powder diffraction (XRPD), differential scanning calorimetry (DSC), zeta potentials, polydispersity indexes, and dissolution studies. F10 was the optimized formulation that showed stability at room temperature, as well as at a refrigerated temperature, for 30 days. A high dissolution rate (100% within the first 10 min) was shown by comparative dissolution studies of nano-suspensions with the micro-suspension and raw loxoprofen. F10 formulation had a non-porous and crystalline morphology on evaluation by TEM and XRPD, respectively, and the average particle size was 300 ± 0.3 nm as confirmed by TEM. DSC recorded a reduction in the melting point (180 °C processed and 200 °C unprocessed melting points). The dissolution rate and solubility of the formulated loxoprofen nanocrystals were significantly enhanced. It can be concluded that selecting suitable stabilizers (i.e., polymers and surfactants) can produce stable nanocrystals, and this can potentially lead to a scaling up of the process for commercialization. Full article

The aim of this research was to evaluate the mechanical impact of different direct restorations in terms of fracture resistance, and subsequent fracture pattern, in occlusal high C-factor cavities. Furthermore, the adaptation of different direct restorations in the form of gap formation was also evaluated. Seventy-two intact mandibular molars were collected and randomly distributed into three groups (n = 24). Class I occlusal cavities with standardized dimensions were prepared in all specimens. After adhesive treatment, the cavities were restored with direct restorations utilizing three different materials. Group 1: layered conventional packable resin composite (Filtek Ultimate), Group 2: bulk-fill resin composite (SDR), Group 3: bulk-fill short fibre-reinforced composite (SFRC; everX Posterior) covered with packable composite occlusally. Half of the restored specimens underwent static load-to fracture testing (n = 12/group), while the rest underwent sectioning and staining for microleakage evaluation and gap formation analysis. Fracture patterns were evaluated visually among the mechanically tested specimens. The layered composite restoration (Group 1) showed significantly lower fracture resistance compared to the bulk fill groups (Group 2, p = 0.005, Group 3, p = 0.008), while there was no difference in fracture resistance between the other groups. In terms of gap formation values, the layered composite restoration (Group 1) produced significantly higher gap formation compared to the bulk-fill groups (Group 2, p = 0.000, Group 3, p = 0.000). Regarding the fracture pattern, SFRC (Group 3) produced the highest number, while SDR (Group 2) produced the lowest number of repairable fractures. The use of bulk-fill resin composite (fibre or non-fibre-reinforced) for occlusal direct restorations in high C-factor cavities showed promising achievements regarding both fracture resistance and microleakage. Furthermore, the use of short fibre-reinforced bulk-fill composite can also improve the fracture pattern of the restoration-tooth unit. Bulk-fill materials provide a simple and effective solution for restoring and reinforcing high C-factor occlusal cavities. Full article

Potatoes are a source of starch, which is an eco-friendly alternative to petrochemicals in plastic production. Increasing potato production also creates agricultural waste that could be converted to potato peel starch (PPS) and developed as films. A response surface method approach was employed to optimize the bioconversion of PPS (2, 4, and 6% w/v) and compared with carboxymethyl cellulose (CMC)-based films. The microstructure analysis of PPSF showed increased thickness, decreased swelling power, water solubility, and vapor permeability, which were linked to increased molecular interactions as a function of PPS increments. However, low-starch PPSF exhibited high transparency, good mechanical properties, and thermal stability (high melting temperature), pliability, and accelerated seawater and soil biodegradation (~90%: 20 and 50 days, respectively). All films exhibited thermal stability at >100 °C and retained similar amorphous characteristics, evidenced by their flexibility, which confirmed the potential use for PPS in packaging perishable and cooled foods. Full article