Silicon for High-Energy Lithium Ion Batteries

A special issue of Batteries (ISSN 2313-0105).

Deadline for manuscript submissions: closed (31 December 2018) | Viewed by 7855

Special Issue Editor


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Guest Editor
Helmholtz-Institut Münster (HI MS), Forschungszentrum Jülich (FZJ), Julich, Germany
Interests: silicon alloys; ageing of batteries innovation and technology transfer; carbon nano-materials in battery applications; model parametrization for batteries

Special Issue Information

Dear Colleagues,

Since its introduction into the market by Sony in 1991, Lithium-ion battery technology has made rapid progress with respect to energy density. This development has facilitated numerous applications and a multi-billion dollar market. The increase in energy has mainly been achieved by engineering efforts focusing on thinner separators, current collectors and decreased porosities of the electrodes, whereas the materials system consisting of Lithium cobalt(III) oxide (LCO) and graphite as active cathode and anode materials, respectively, has not been altered. Nevertheless, these optimizations have reached physical limits, but the need for cells with even higher capacities for electronics and automotive applications is ever-growing. Therefore, high capacity materials like Silicon for anodes have received renewed attention during the last years. Moreover, Silicon has recently materialized in commercial Lithium ion battery cells for a boost of energy, though the absolute amount of Silicon is rather low in such cells due to Silicon specific degradation issues. Therefore there is a significant need for an improved understanding of the behavior of Silicon in Lithium ion battery cells and for innovative Silicon materials leading to improved lifetime and high energy density.

The Special Issue of Batteries will summarize the most recent developments and scientific contributions in the field of “Silicon for High-Energy Lithium Ion Batteries”. Contributions will cover both, fundamental and applied aspects of Silicon materials in the context of Lithium ion batteries:

  • Silicon alloy materials
  • Silicon-graphite blend materials
  • Degradation mechanisms of Silicon-modified electrodes
  • SEI-layer formation on Silicon-modified electrodes
  • Electrolyte additives for Silicon-modified electrodes

Prof. Dr. Egbert Figgemeier
Guest Editor

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Keywords

  • Li batteries
  • Silicon alloys
  • High capacity anodes
  • Electrolyte additives for Si-based anodes
  • Binders for Si-based anodes
  • Production of Si-based anodes
  • Degradation of Silicon based electrodes
  • Commercial aspect of Silicon-modified batteries

Published Papers (1 paper)

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Research

12 pages, 2330 KiB  
Article
Silicon/Mesoporous Carbon (Si/MC) Derived from Phenolic Resin for High Energy Anode Materials for Li-ion Batteries: Role of HF Etching and Vinylene Carbonate (VC) Additive
by Arlavinda Rezqita, Hristina Vasilchina, Raad Hamid, Markus Sauer, Annette Foelske, Corina Täubert and Hermann Kronberger
Batteries 2019, 5(1), 11; https://doi.org/10.3390/batteries5010011 - 16 Jan 2019
Cited by 3 | Viewed by 7487
Abstract
Silicon/mesoporous carbon (Si/MC) composites with optimum Si content, in which the volumetric energy density would be maximized, while volume changes would be minimized, have been developed. The composites were prepared by dispersing Si nanoparticles in a phenolic resin as a carbon source, subsequent [...] Read more.
Silicon/mesoporous carbon (Si/MC) composites with optimum Si content, in which the volumetric energy density would be maximized, while volume changes would be minimized, have been developed. The composites were prepared by dispersing Si nanoparticles in a phenolic resin as a carbon source, subsequent carbonization, and etching with hydrofluoric acid (HF). Special attention was paid to understanding the role of HF etching as post-treatment to provide additional void spaces in the composites. The etching process was shown to reduce the SiO2 native layer on the Si nanoparticles, resulting in increased porosity in comparison to the non-etched composite material. For cell optimization, vinylene carbonate (VC) was employed as an electrolyte additive to build a stable solid electrolyte interphase (SEI) layer on the electrode. The composition of the SEI layer on Si/MC electrodes, cycled with and without VC-containing electrolytes for several cycles, was then comprehensively investigated by using ex-situ XPS. The SEI layers on the electrodes working with VC-containing electrolyte were more stable than those in configurations without VC; this explains why our sample with VC exhibits lower irreversible capacity losses after several cycles. The optimized Si/MC composites exhibit a reversible capacity of ~800 mAhg−1 with an average coulombic efficiency of ~99 % over 400 cycles at C/10. Full article
(This article belongs to the Special Issue Silicon for High-Energy Lithium Ion Batteries)
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