Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor
AbstractDuring the last years there has been a high interest in the development of new purely-organic single-component conductors. Very recently, we have reported a new neutral radical conductor based on the perchlorotriphenylmethyl (PTM) radical moiety linked to a monopyrrolo-tetrathiafulvalene (MPTTF) unit by a π-conjugated bridge (1) that behaves as a semiconductor under high pressure. With the aim of developing a new material with improved conducting properties, we have designed and synthesized the radical dyad 2 which was functionalized with an ethylenedithio (EDT) group in order to improve the intermolecular interactions of the tetrathiafulvalene (TTF) subunits. The physical properties of the new radical dyad 2 were studied in detail in solution to further analyze its electronic structure. View Full-Text
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Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry 2016, 2, 46.
Souto M, Bendixen D, Jensen M, Díez-Cabanes V, Cornil J, Jeppesen JO, Ratera I, Rovira C, Veciana J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry. 2016; 2(4):46.Chicago/Turabian Style
Souto, Manuel; Bendixen, Dan; Jensen, Morten; Díez-Cabanes, Valentín; Cornil, Jérôme; Jeppesen, Jan O.; Ratera, Imma; Rovira, Concepció; Veciana, Jaume. 2016. "Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor." Magnetochemistry 2, no. 4: 46.
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