Next Article in Journal
Elaboration of Luminescent and Magnetic Hybrid Networks Based on Lanthanide Ions and Imidazolium Dicarboxylate Salts: Influence of the Synthesis Conditions
Next Article in Special Issue
Mn‐Containing Paramagnetic Conductors with Bis(ethylenedithio)tetrathiafulvalene (BEDT‐TTF)
Previous Article in Journal
Perspectives on Neutron Scattering in Lanthanide-Based Single-Molecule Magnets and a Case Study of the Tb2(μ-N2) System
Article Menu

Export Article

Open AccessFeature PaperArticle
Magnetochemistry 2016, 2(4), 46; doi:10.3390/magnetochemistry2040046

Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor

1
Department of Molecular Nanoscience and Organic Materials, Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN, Campus de la UAB, 08193 Bellaterra, Spain
2
Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, 5230 Odense, Denmark
3
Laboratory for the Chemistry of Novel Materials, Université de Mons, 7000 Mons, Belgium
*
Authors to whom correspondence should be addressed.
Academic Editor: Manuel Almeida
Received: 3 November 2016 / Revised: 7 December 2016 / Accepted: 9 December 2016 / Published: 16 December 2016
(This article belongs to the Special Issue Magnetism of Molecular Conductors)
View Full-Text   |   Download PDF [2891 KB, uploaded 16 December 2016]   |  

Abstract

During the last years there has been a high interest in the development of new purely-organic single-component conductors. Very recently, we have reported a new neutral radical conductor based on the perchlorotriphenylmethyl (PTM) radical moiety linked to a monopyrrolo-tetrathiafulvalene (MPTTF) unit by a π-conjugated bridge (1) that behaves as a semiconductor under high pressure. With the aim of developing a new material with improved conducting properties, we have designed and synthesized the radical dyad 2 which was functionalized with an ethylenedithio (EDT) group in order to improve the intermolecular interactions of the tetrathiafulvalene (TTF) subunits. The physical properties of the new radical dyad 2 were studied in detail in solution to further analyze its electronic structure. View Full-Text
Keywords: neutral organic radical; perchlorotriphenylmethyl radical; tetrathiafulvalene; donor-acceptor neutral organic radical; perchlorotriphenylmethyl radical; tetrathiafulvalene; donor-acceptor
Figures

Figure 1

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Supplementary material

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry 2016, 2, 46.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Magnetochemistry EISSN 2312-7481 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top