Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand
AbstractIsostructural Ln(III) mononuclear complexes [Ln(NO3)2L]PF6·MeCN (Ln = Nd, Tb, or Dy; L denotes a helical hexa-dentate ligand) were synthesized, and their slow magnetic relaxation behavior was investigated. In these complexes, oblate-type Ln(III) ions are located in an axially stressed ligand field with two nitrate anions, and can exhibit single-molecule magnet (SMM) behavior. Field-induced SMM behavior was observed for Nd(III) and Dy(III) complexes under an applied bias DC field of 1000 Oe. View Full-Text
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Wada, H.; Ooka, S.; Iwasawa, D.; Hasegawa, M.; Kajiwara, T. Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand. Magnetochemistry 2016, 2, 43.
Wada H, Ooka S, Iwasawa D, Hasegawa M, Kajiwara T. Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand. Magnetochemistry. 2016; 2(4):43.Chicago/Turabian Style
Wada, Hisami; Ooka, Sayaka; Iwasawa, Daichi; Hasegawa, Miki; Kajiwara, Takashi. 2016. "Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand." Magnetochemistry 2, no. 4: 43.
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