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Magnetochemistry 2016, 2(4), 43; doi:10.3390/magnetochemistry2040043

Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand

1
Department of Chemistry, Faculty of Science, Nara Women’s University, Kita-uoya Nishi-machi, Nara 630-8506, Japan
2
Department of Chemistry and Biological Science, College of Science and Engineering, Aoyama Gakuin University, Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan
*
Authors to whom correspondence should be addressed.
Academic Editor: Kevin Bernot
Received: 31 October 2016 / Revised: 28 November 2016 / Accepted: 30 November 2016 / Published: 8 December 2016
(This article belongs to the Special Issue Molecular Magnetism of Lanthanides Complexes and Networks)
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Abstract

Isostructural Ln(III) mononuclear complexes [Ln(NO3)2L]PF6·MeCN (Ln = Nd, Tb, or Dy; L denotes a helical hexa-dentate ligand) were synthesized, and their slow magnetic relaxation behavior was investigated. In these complexes, oblate-type Ln(III) ions are located in an axially stressed ligand field with two nitrate anions, and can exhibit single-molecule magnet (SMM) behavior. Field-induced SMM behavior was observed for Nd(III) and Dy(III) complexes under an applied bias DC field of 1000 Oe. View Full-Text
Keywords: lanthanide complex; slow magnetic relaxation; single-molecule magnet; crystal structure; AC susceptibility lanthanide complex; slow magnetic relaxation; single-molecule magnet; crystal structure; AC susceptibility
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MDPI and ACS Style

Wada, H.; Ooka, S.; Iwasawa, D.; Hasegawa, M.; Kajiwara, T. Slow Magnetic Relaxation of Lanthanide(III) Complexes with a Helical Ligand. Magnetochemistry 2016, 2, 43.

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