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Magnetochemistry 2016, 2(4), 41; doi:10.3390/magnetochemistry2040041

Magneto-Luminescence Correlation in the Textbook Dysprosium(III) Nitrate Single-Ion Magnet

1
Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objects, Université de Montpellier, ENSCM, CNRS, Place E. Bataillon, 34095 Montpellier CEDEX 5, France
2
Physics Department and CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal
3
I3N, University of Aveiro, 3810-193 Aveiro, Portugal
4
Laboratoire des Multimatériaux et Interfaces (UMR 5616), Université Claude Bernard Lyon 1, Campus de la Doua, 69622 CEDEX Villeurbanne, France
*
Author to whom correspondence should be addressed.
Academic Editor: Kevin Bernot
Received: 11 October 2016 / Revised: 10 November 2016 / Accepted: 12 November 2016 / Published: 18 November 2016
(This article belongs to the Special Issue Molecular Magnetism of Lanthanides Complexes and Networks)
View Full-Text   |   Download PDF [2111 KB, uploaded 18 November 2016]   |  

Abstract

Multifunctional Single-Molecule Magnets (SMMs) or Single-Ion Magnets (SIMs) are intriguing molecule-based materials presenting an association of the slow magnetic relaxation with other physical properties. In this article, we present an example of a very simple molecule based on Dy3+ ion exhibiting a field induced SIM property and a characteristic Dy3+ based emission. The [Dy(NO3)3(H2O)4]·2H2O (1) complex is characterized by the means of single crystal X-Ray diffraction and their magnetic and photo-luminescent properties are investigated. We demonstrate here that it is possible to correlate the magnetic and luminescent properties and to obtain the Orbach barrier from the low temperature emission spectra, which is often difficult to properly extract from the magnetic measurements, especially in the case of field induced SIMs. View Full-Text
Keywords: lanthanides; single-ion magnets; single-molecule magnet; luminescence; magnetic relaxation lanthanides; single-ion magnets; single-molecule magnet; luminescence; magnetic relaxation
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Mamontova, E.; Long, J.; Ferreira, R.A.S.; Botas, A.M.P.; Luneau, D.; Guari, Y.; Carlos, L.D.; Larionova, J. Magneto-Luminescence Correlation in the Textbook Dysprosium(III) Nitrate Single-Ion Magnet. Magnetochemistry 2016, 2, 41.

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