UV Light-Assisted Synthesis of Highly Efficient Pd-Based Catalyst over NiO for Hydrogenation of o-Chloronitrobenzene
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents and Chemicals
2.2. Preparation of Active NiO Powders
2.3. Preparation of Pd-Based Catalysts over NiO Particles
2.4. Catalyst Characterizations
2.5. Catalyst Evaluation
2.6. Product Analysis
3. Results
3.1. Preparation and Characterizations of Various Pd-Based Catalysts
3.2. Positive Effect of UV-Light Irradiation
3.3. Effect of Pd Loading
3.4. Effect of Molar Ratios of o-CNB to Pd
3.5. Effect of Reaction Time
3.6. Effect of Reaction Temperature
3.7. Effect of Hydrogen Pressure
3.8. Recycling Test of UV-Irradiated Pd-Base Catalyst
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Catalyst | Surface Area (m2/g) | Pore Volume (cc/g) | Pore Diameter (Å) |
---|---|---|---|
NiO | 25.07 | 0.178 | 141.9 |
0.1% Pd/NiO a | 25.17 | 0.177 | 139.3 |
0.2% Pd/NiO a | 25.29 | 0.175 | 138.2 |
0.3% Pd/NiO a | 25.44 | 0.173 | 137.5 |
0.2% Pd/NiO b | 104.7 | 0.200 | 35.9 |
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Jiang, W.; Xu, B.; Fan, G.; Zhang, K.; Xiang, Z.; Liu, X. UV Light-Assisted Synthesis of Highly Efficient Pd-Based Catalyst over NiO for Hydrogenation of o-Chloronitrobenzene. Nanomaterials 2018, 8, 240. https://doi.org/10.3390/nano8040240
Jiang W, Xu B, Fan G, Zhang K, Xiang Z, Liu X. UV Light-Assisted Synthesis of Highly Efficient Pd-Based Catalyst over NiO for Hydrogenation of o-Chloronitrobenzene. Nanomaterials. 2018; 8(4):240. https://doi.org/10.3390/nano8040240
Chicago/Turabian StyleJiang, Weidong, Bin Xu, Guangyin Fan, Kaiming Zhang, Zhen Xiang, and Xiaoqiang Liu. 2018. "UV Light-Assisted Synthesis of Highly Efficient Pd-Based Catalyst over NiO for Hydrogenation of o-Chloronitrobenzene" Nanomaterials 8, no. 4: 240. https://doi.org/10.3390/nano8040240