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Membranes 2014, 4(2), 210-226; doi:10.3390/membranes4020210
Article

Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide)

 and *
Received: 10 March 2014; in revised form: 8 April 2014 / Accepted: 18 April 2014 / Published: 30 April 2014
(This article belongs to the Special Issue Advances in Liquid Membranes)
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Abstract: A polymeric pseudo-liquid membrane (PPLM) was constructed from poly(N-oleylacrylamide) (PC18AAm), which exhibited a rubbery state under membrane transport conditions and used as the membrane matrix. In the present study, dibenzo-18-crown-6 (DB18C6) and dibenzo-21-crown-7 (DB21C7) were adopted as transporters for alkali metal ions. KCl was adopted as a model substrate for DB18C6 and CsCl the latter. Chiral transporter, O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (AAMC) was used as a transporter for chiral separation of a racemic mixture of phenylglycine (Phegly). The l-somer was transported in preference to the antipode. The present study revealed that PPLMs are applicable to membrane transport, such as metal ion transport and chiral separation.
Keywords: cesium ions; chiral separation; crown ether; liquid membrane; phenylglycine; polymeric pseudo-liquid membrane; poly(N-oleylacrylamide); potassium ions cesium ions; chiral separation; crown ether; liquid membrane; phenylglycine; polymeric pseudo-liquid membrane; poly(N-oleylacrylamide); potassium ions
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Shiono, H.; Yoshikawa, M. Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide). Membranes 2014, 4, 210-226.

AMA Style

Shiono H, Yoshikawa M. Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide). Membranes. 2014; 4(2):210-226.

Chicago/Turabian Style

Shiono, Hiroko; Yoshikawa, Masakazu. 2014. "Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide)." Membranes 4, no. 2: 210-226.



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