Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide)
AbstractA polymeric pseudo-liquid membrane (PPLM) was constructed from poly(N-oleylacrylamide) (PC18AAm), which exhibited a rubbery state under membrane transport conditions and used as the membrane matrix. In the present study, dibenzo-18-crown-6 (DB18C6) and dibenzo-21-crown-7 (DB21C7) were adopted as transporters for alkali metal ions. KCl was adopted as a model substrate for DB18C6 and CsCl the latter. Chiral transporter, O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (AAMC) was used as a transporter for chiral separation of a racemic mixture of phenylglycine (Phegly). The l-somer was transported in preference to the antipode. The present study revealed that PPLMs are applicable to membrane transport, such as metal ion transport and chiral separation.
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Shiono, H.; Yoshikawa, M. Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide). Membranes 2014, 4, 210-226.
Shiono H, Yoshikawa M. Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide). Membranes. 2014; 4(2):210-226.Chicago/Turabian Style
Shiono, Hiroko; Yoshikawa, Masakazu. 2014. "Polymeric Pseudo-Liquid Membranes from Poly(N-oleylacrylamide)." Membranes 4, no. 2: 210-226.