An Experimental Study of a Zeolite Membrane Reactor for Reverse Water Gas Shift
Abstract
:1. Introduction
2. Experimental
2.1. Catalyst Preparation
2.2. Membrane Preparation
2.3. Membrane Reactor Test
3. Results and Discussion
3.1. Characterizations of Catalyst and Membrane
3.2. Permeation and Separation Properties of MFI Zeolite for H2O/H2 and H2O/CO2
3.3. RWGS Membrane Reactor Tests
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
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System | Temperature/K | Permeance/10−7 mol m−2 s−1 Pa−1 | Separation Factor/- | ||
---|---|---|---|---|---|
H2O | H2 | CO2 | |||
H2O | 523 | 3.89 | - | - | |
623 | 3.58 | - | - | ||
H2 | 523 | - | 1.73 | - | |
623 | - | 2.68 | - | ||
CO2 | 523 | - | - | 1.31 | |
623 | - | - | 1.60 | ||
H2O/H2 | 523 | 2.99 | 0.154 | - | 17.2 |
623 | 1.78 | 0.204 | - | 8.11 | |
H2O/CO2 | 523 | 3.64 | - | 0.182 | 17.8 |
623 | 2.24 | - | 0.180 | 11.6 |
Configuration | Carbon Balance/% | ||||
---|---|---|---|---|---|
515 K | 538 K | 560 K | 586 K | 609 K | |
Case 1 | 101.0 | 100.6 | 99.8 | 99.8 | 99.7 |
Case 2 | 100.7 | 100.4 | 103.4 | 100.1 | 102.1 |
Case 3 | 98.1 | 99.6 | 99.4 | 98.0 | 99.0 |
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Sakai, M.; Tanaka, K.; Matsukata, M. An Experimental Study of a Zeolite Membrane Reactor for Reverse Water Gas Shift. Membranes 2022, 12, 1272. https://doi.org/10.3390/membranes12121272
Sakai M, Tanaka K, Matsukata M. An Experimental Study of a Zeolite Membrane Reactor for Reverse Water Gas Shift. Membranes. 2022; 12(12):1272. https://doi.org/10.3390/membranes12121272
Chicago/Turabian StyleSakai, Motomu, Kyoka Tanaka, and Masahiko Matsukata. 2022. "An Experimental Study of a Zeolite Membrane Reactor for Reverse Water Gas Shift" Membranes 12, no. 12: 1272. https://doi.org/10.3390/membranes12121272