Fluorinated and Non-Fluorinated Electro-Optic Copolymers: Determination of the Time and Temperature Stability of the Induced Electro-Optic Coefficient

Abstract: Organic fluorinated materials demonstrate their excellent electro-optic properties and versatility for technological applications. The partial substitution of hydrogen with fluorine in carbon-halides bounds allows the reduction of absorption losses at the telecommunication wavelengths. In these interesting compounds, the electro-optic coefficient was typically induced by a poling procedure. The magnitude and the time stability of the coefficient is an important issue to be investigated in order to compare copolymer species. Here, a review of different measurement techniques (such as nonlinear ellipsometry, second harmonic generation, temperature scanning and isothermal relaxation) was shown and applied to a variety of fluorinated and non-fluorinated electro-optic compounds.