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Polymers 2017, 9(12), 649; doi:10.3390/polym9120649

Synthesis and Characterization of Dimmer-Acid-Based Nonisocyanate Polyurethane and Epoxy Resin Composite

Key Laboratory of Molecular Biophysics of the Ministry of Education, College of Life Science and echnology, Huazhong University of Science and Technology, Wuhan 430074, China
Author to whom correspondence should be addressed.
Received: 7 November 2017 / Revised: 24 November 2017 / Accepted: 24 November 2017 / Published: 28 November 2017
(This article belongs to the Special Issue Biodegradable and Biobased Polyesters)
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In this study, dimmer-acid-based hybrid nonisocyanate polyurethanes (HNIPUs) were synthesized by the one-step method without catalyst. Three polyamines and two epoxy resins were selected as raw materials for HNIPU, and cyclic carbonate was synthesized based on our previous work. All of the products were characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Then, HNIPU coatings were prepared and determined by swelling, water absorption, and water contact angle. The results showed that the HNIPU-4551 have the best mechanical and thermal properties because of its high crosslinking density. Among the different amines, it was confirmed that tetraethylenepentamine was the best amine curing agent for HNIPU coating. Meanwhile, the epoxy resin with a higher epoxy value would also form a higher crosslinking density. Those coatings showed an excellent impact strength, adhesion, flexibility, pencil hardness, hydrophilic, and appropriate crosslinking density. View Full-Text
Keywords: hybrid nonisocyanate polyurethane; dimer acid; epoxy resin; coating hybrid nonisocyanate polyurethane; dimer acid; epoxy resin; coating

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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He, X.; Xu, X.; Wan, Q.; Bo, G.; Yan, Y. Synthesis and Characterization of Dimmer-Acid-Based Nonisocyanate Polyurethane and Epoxy Resin Composite. Polymers 2017, 9, 649.

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