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Polymers 2017, 9(12), 693; https://doi.org/10.3390/polym9120693

Catalyst Influence on Undesired Side Reactions in the Polycondensation of Fully Bio-Based Polyester Itaconates

Fraunhofer Institute for Wood Research–Wilhelm-Klauditz-Institut WKI, Bienroder Weg 54E, 38108 Braunschweig, Germany
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Received: 17 November 2017 / Revised: 5 December 2017 / Accepted: 6 December 2017 / Published: 9 December 2017
(This article belongs to the Special Issue Biodegradable and Biobased Polyesters)
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Abstract

Bio-based unsaturated polyester resins derived from itaconic acid can be an alternative to established resins of this type in the field of radical-curing resins. However, one of the challenges of these polyester itaconates is the somewhat more elaborate synthetic process, especially under polycondensation conditions used on an industrial scale. The α,β-unsaturated double bond of the itaconic acid is prone to side reactions that can lead to the gelation of the polyester resin under standard conditions. This is especially true when bio-based diols such as 1,3-propanediol or 1,4-butanediol are used to obtain resins that are 100% derived from renewable resources. It was observed in earlier studies that high amounts of these aliphatic diols in the polyester lead to low conversion and gelation of the resins. In this work, a catalytic study using different diols was performed in order to elucidate the reasons for this behavior. It was shown that the choice of catalyst has a crucial influence on the side reactions occurring during the polycondensation reactions. In addition, the side reactions taking place were identified and suppressed. These results will allow for the synthesis of polyester itaconates on a larger scale, setting the stage for their industrial application. View Full-Text
Keywords: bio-based polyester; itaconic acid; polyester; Ordelt-reaction; UV-curing materials bio-based polyester; itaconic acid; polyester; Ordelt-reaction; UV-curing materials
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Schoon, I.; Kluge, M.; Eschig, S.; Robert, T. Catalyst Influence on Undesired Side Reactions in the Polycondensation of Fully Bio-Based Polyester Itaconates. Polymers 2017, 9, 693.

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