Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid
Abstract
:1. Introduction
2. Results and Discussion
2.1. Crystal Structure of C16py-W10
Chemical formula | C84H152N4W10O32 |
Formula weight | 3568.54 |
Crystal system | triclinic |
Space group | P (No.2) |
a (Å) | 10.7727 (12) |
b (Å) | 11.3734 (12) |
c (Å) | 23.982 (3) |
α (°) | 98.566 (4) |
β (°) | 95.298 (4) |
γ (°) | 116.168 (4) |
V (Å3) | 2566.1 (5) |
Z | 1 |
ρcalcd (g cm−3) | 2.309 |
T (K) | 213 (2) |
μ (Mo Kα) (mm−1) | 11.230 |
No. of reflections measured | 41418 |
No. of independent reflections | 11736 |
Rint | 0.0635 |
No. of parameters | 587 |
R1 (I > 2σ(I)) | 0.0354 |
wR2 (all data) | 0.0842 |
H···O (Ǻ) | C···O (Ǻ) | C-H···O (deg) | |
---|---|---|---|
C1 i–H1 i···O15 | 2.967(5) | 3.880(9) | 164.3(5) |
C28 i–H28B i···O8 | 2.410(4) | 3.318(7) | 154.1(4) |
C28–H28A···O5 | 2.795(3) | 3.730(6) | 159.8(4) |
C3–H3···O2 | 2.634(4) | 3.550(8) | 164.7(5) |
C21 iii–H21A iii···O2 | 2.476(4) | 3.380(11) | 155.2(5) |
C26–H26···O4 | 2.534(4) | 3.448(7) | 164.5(5) |
C6 ii–H6A ii···O4 | 2.384(5) | 3.278(9) | 151.3(4) |
2.2. Powder X-Ray Diffraction (XRD) Patterns of C16py-W10
2.3. Conductivity of C16py-W10
3. Experimental Section
3.1. Syntheses and Methods
3.2. X-ray Diffraction Measurements
4. Conclusions
Acknowledgments
References and Notes
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Ito, T.; Fujimoto, N.; Uchida, S.; Iijima, J.; Naruke, H.; Mizuno, N. Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid. Crystals 2012, 2, 362-373. https://doi.org/10.3390/cryst2020362
Ito T, Fujimoto N, Uchida S, Iijima J, Naruke H, Mizuno N. Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid. Crystals. 2012; 2(2):362-373. https://doi.org/10.3390/cryst2020362
Chicago/Turabian StyleIto, Takeru, Nozomu Fujimoto, Sayaka Uchida, Jun Iijima, Haruo Naruke, and Noritaka Mizuno. 2012. "Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid" Crystals 2, no. 2: 362-373. https://doi.org/10.3390/cryst2020362