Next Article in Journal
Crystal Structure of the 5-Chloro Salicylamides: Three Different Types of the H-bonding Influenced Linear Chain Formation in the Solid State
Next Article in Special Issue
Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid
Previous Article in Journal / Special Issue
Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs
Article Menu

Export Article

Open AccessArticle
Crystals 2012, 2(2), 338-348; doi:10.3390/cryst2020338

Electroactive Bisiminopyridine Ligands: Synthesis and Complexation Studies

CIMI group, Laboratoire MOLTECH-Anjou, CNRS UMR 6200, Université d’Angers, LUNAM Université, 2 bd Lavoisier, 49045 ANGERS cedex, France
*
Authors to whom correspondence should be addressed.
Received: 22 March 2012 / Revised: 6 April 2012 / Accepted: 9 April 2012 / Published: 24 April 2012
(This article belongs to the Special Issue Molecular Conductors)
View Full-Text   |   Download PDF [639 KB, uploaded 24 April 2012]   |  

Abstract

The condensation reaction of (4-(6,7-dimethyldithio-tetrathiafulvalene)-aniline) with 2,6-diformylpyridine afforded an electroactive Schiff base (N,N,N) pincer (3). This pincer was reacted with Zn(II) cation to yield the corresponding Zinc chloride complex (4). The crystal structure of the newly prepared electroactive zinc complex reveals that the tetrathiafulvalene (TTF) is neutral and the zinc cation is pentacoordinated. The two chlorines are involved in a set of hydrogen bonds giving rise to a 2D supramolecular grid arrangement. The electronic absorption properties and the electrochemical behavior have been elucidated. These two compounds are promising for the construction of crystalline radical cation salts.
Keywords: tetrathiafulvalene; Schiff base; transition metal complex; cyclic voltammetry; UV-Vis spectroscopy tetrathiafulvalene; Schiff base; transition metal complex; cyclic voltammetry; UV-Vis spectroscopy
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Supplementary material

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Nita, G.; Branzea, D.; Pop, F.; El-Ghayoury, A.; Avarvari, N. Electroactive Bisiminopyridine Ligands: Synthesis and Complexation Studies. Crystals 2012, 2, 338-348.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Crystals EISSN 2073-4352 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top