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Catalysts 2015, 5(4), 2287-2308; doi:10.3390/catal5042287

Experimental and Modeling Studies on the Conversion of Inulin to 5-Hydroxymethylfurfural Using Metal Salts in Water

1
Chemical Engineering Department, University of Groningen, Nijenborg 4, 9747 AG Groningen, The Netherlands
2
Faculty of Engineering, University of Jember, Jember 58121, Indonesia
3
Chemical Engineering Department, Bandung Institute of Technology, Bandung 40132, Indonesia
These authors contributed equally to this work.
*
Author to whom correspondence should be addressed.
Academic Editor: Rafael Luque
Received: 24 October 2015 / Revised: 12 December 2015 / Accepted: 14 December 2015 / Published: 21 December 2015
(This article belongs to the Special Issue Catalytic Conversion of Biomass)
View Full-Text   |   Download PDF [1021 KB, uploaded 21 December 2015]   |  

Abstract

Inulin, a plant polysaccharide consisting of mainly d-fructose units, is considered an interesting feed for 5-hydroxymethylfurfural (HMF), a top 12 bio-based chemical. We here report an exploratory experimental study on the use of a wide range of homogeneous metal salts as catalysts for the conversion of inulin to HMF in water. Best results were obtained using CuCl2. Activity-pH relations indicate that the catalyst activity of CuCl2 is likely related to Lewis acidity and not to Brönsted acidity. The effects of process conditions on HMF yield for CuCl2 were systematically investigated and quantified using a central composite design (160–180 °C, an inulin loading between 0.05 and 0.15 g/mL, CuCl2 concentration in range of 0.005–0.015 M, and a reaction time between 10 and 120 min). The highest experimental HMF yield in the process window was 30.3 wt. % (39 mol %, 180 °C, 0.05 g/mL inulin, 0.005 M CuCl2 and a reaction time of 10 min). The HMF yields were modelled using non-linear, multi variable regression and good agreement between experimental data and model were obtained. View Full-Text
Keywords: inulin; metal salts; HMF; levulinic acid; CuCl2 inulin; metal salts; HMF; levulinic acid; CuCl2
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Fachri, B.A.; Rasrendra, C.B.; Heeres, H.J. Experimental and Modeling Studies on the Conversion of Inulin to 5-Hydroxymethylfurfural Using Metal Salts in Water. Catalysts 2015, 5, 2287-2308.

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