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Materials 2015, 8(5), 2258-2275; doi:10.3390/ma8052258

Low-Pressure H2, NH3 Microwave Plasma Treatment of Polytetrafluoroethylene (PTFE) Powders: Chemical, Thermal and Wettability Analysis

Institute for Materials Research & Innovation (IMRI), University of Bolton, Deane Road, Bolton BL3 5AB, UK
Institute of Polymer Engineering, University of Applied Sciences (UAS), Northwestern Switzerland, 5210 Windisch, Switzerland
Center for Lipid Research, Indian Institute of Chemical Technology (IICT), Hyderabad 500007, India
Author to whom correspondence should be addressed.
Academic Editor: Reza Montazami
Received: 1 March 2015 / Revised: 16 April 2015 / Accepted: 20 April 2015 / Published: 28 April 2015
(This article belongs to the Special Issue Smart Materials)
View Full-Text   |   Download PDF [3766 KB, uploaded 28 April 2015]   |  


Functionalization of Polytetrafluoroethylene (PTFE) powders of ~6 μm particle size is carried out using low-pressure 2.45 GHz H2, NH3 microwave plasmas for various durations (2.5, 10 h) to chemically modify their surface and alter their surface energy. The X-ray Photoelectron Spectroscopy (XPS) analyses reveal that plasma treatment leads to significant defluorination (F/C atomic ratio of 1.13 and 1.30 for 10 h NH3 and H2 plasma treatments, respectively vs. 1.86 for pristine PTFE), along with the incorporation of functional polar moieties on the surface, resulting in enhanced wettability. Analysis of temperature dependent XPS revealed a loss of surface moieties above 200 °C, however, the functional groups are not completely removable even at higher temperatures (>300 °C), thus enabling the use of plasma treated PTFE powders as potential tribological fillers in high temperature engineering polymers. Ageing studies carried over a period of 12 months revealed that while the surface changes degenerate over time, again, they are not completely reversible. These functionalised PTFE powders can be further used for applications into smart, high performance materials such as tribological fillers for engineering polymers and bio-medical, bio-material applications. View Full-Text
Keywords: polytetrafluoroethylene (PTFE); low-pressure microwave plasma; ESCA/XPS; degeneration; thermal stability polytetrafluoroethylene (PTFE); low-pressure microwave plasma; ESCA/XPS; degeneration; thermal stability

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Hunke, H.; Soin, N.; Shah, T.H.; Kramer, E.; Pascual, A.; Karuna, M.S.L.; Siores, E. Low-Pressure H2, NH3 Microwave Plasma Treatment of Polytetrafluoroethylene (PTFE) Powders: Chemical, Thermal and Wettability Analysis. Materials 2015, 8, 2258-2275.

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