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Materials 2012, 5(12), 2537-2572; doi:10.3390/ma5122537
Review

Solid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs)

1
, 1
, 2
, 1
, 2
, 2
 and 1,*
1 Department of Chemistry and Food Chemistry, Bioanalytical Chemistry, Dresden University of Technology, Dresden 01062, Germany 2 Department of Chemistry and Food Chemistry, Inorganic Chemistry I, Dresden University of Technology, Dresden 01062, Germany
* Author to whom correspondence should be addressed.
Received: 10 October 2012 / Revised: 13 November 2012 / Accepted: 20 November 2012 / Published: 28 November 2012
(This article belongs to the Special Issue NMR in Materials Science)
Download PDF [2414 KB, uploaded 28 November 2012]

Abstract

Nuclear Magnetic Resonance (NMR) spectroscopy is a well-established method for the investigation of various types of porous materials. During the past decade, metal–organic frameworks have attracted increasing research interest. Solid-state NMR spectroscopy has rapidly evolved into an important tool for the study of the structure, dynamics and flexibility of these materials, as well as for the characterization of host–guest interactions with adsorbed species such as xenon, carbon dioxide, water, and many others. The present review introduces and highlights recent developments in this rapidly growing field.
Keywords: metal–organic frameworks; porous materials; solid-state NMR; host–guest interactions; 129Xe NMR metal–organic frameworks; porous materials; solid-state NMR; host–guest interactions; 129Xe NMR
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Hoffmann, H.C.; Debowski, M.; Müller, P.; Paasch, S.; Senkovska, I.; Kaskel, S.; Brunner, E. Solid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs). Materials 2012, 5, 2537-2572.

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