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Materials 2017, 10(7), 747; doi:10.3390/ma10070747

Symmetric Supercapacitor Electrodes from KOH Activation of Pristine, Carbonized, and Hydrothermally Treated Melia azedarach Stones

Departamento de Química Inorgánica, Universidad de Granada, 18071 Granada, Spain
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Received: 1 June 2017 / Revised: 26 June 2017 / Accepted: 29 June 2017 / Published: 4 July 2017
(This article belongs to the Section Energy Materials)
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Abstract

Waste biomass-derived activated carbons (ACs) are promising materials for supercapacitor electrodes due to their abundance and low cost. In this study, we investigated the potential use of Melia azedarach (MA) stones to prepare ACs for supercapacitors. The ash content was considerably lower in MA stones (0.7% ash) than that found in other lignocellulosic wastes. ACs were prepared by KOH activation of pristine, carbonized, and hydrothermally-treated MA stones. The morphology, composition, surface area, porosity, and surface chemistry of the ACs were determined. Electrochemical measurements were carried out in three- and two-electrode cells, 3EC and 2EC, respectively, using 1 M H2SO4 as the electrolyte. The highest capacitance from galvanostatic charge-discharge (GCD) in 2EC ranged between 232 and 240 F·g−1 at 1 A·g−1. The maximum energy density reached was 27.4 Wh·kg−1 at a power density of 110 W·kg−1. Electrochemical impedance spectroscopy (EIS) revealed an increase in equivalent series resistance (ESR) and charge transfer resistance (RCT) with greater ash content. Electrochemical performance of MA stone-derived ACs was compared with that of other ACs described in the recent literature that were prepared from different biomass wastes and results showed that they are among the best ACs for supercapacitor applications. View Full-Text
Keywords: Melia azedarach stones; biomass wastes; activated carbons; supercapacitor electrodes; energy storage Melia azedarach stones; biomass wastes; activated carbons; supercapacitor electrodes; energy storage
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Moreno-Castilla, C.; García-Rosero, H.; Carrasco-Marín, F. Symmetric Supercapacitor Electrodes from KOH Activation of Pristine, Carbonized, and Hydrothermally Treated Melia azedarach Stones. Materials 2017, 10, 747.

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