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Preparation and Properties of Various Magnetic Nanoparticles
Department of Microelectronics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Údolní 53, 602 00 Brno, Czech Republic
Department of Chemistry and Biochemistry, Faculty of Agronomy, Mendel University of Agriculture and Forestry, Zemědělská 1, 613 00 Brno, Czech Republic
Institute of Physics of Materials, Academy of Sciences of the Czech Republic, Zizkova 22, 616 62 Brno, Czech Republic
* Author to whom correspondence should be addressed.
Received: 13 February 2009; in revised form: 23 March 2009 / Accepted: 30 March 2009 / Published: 30 March 2009
Abstract: The fabrications of iron oxides nanoparticles using co-precipitation and gadolinium nanoparticles using water in oil microemulsion method are reported in this paper. Results of detailed phase analysis by XRD and Mössbauer spectroscopy are discussed. XRD analysis revealed that the crystallite size (mean coherence length) of iron oxides (mainly γ-Fe2O3) in the Fe2O3 sample was 30 nm, while in Fe2O3/SiO2 where the ε-Fe2O3 phase dominated it was only 14 nm. Gd/SiO2 nanoparticles were found to be completely amorphous, according to XRD. The samples showed various shapes of hysteresis loops and different coercivities. Differences in the saturation magnetization (MS) correspond to the chemical and phase composition of the sample materials. However, we observed that MS was not reached in the case of Fe2O3/SiO2, while for Gd/SiO2 sample the MS value was extremely low. Therefore we conclude that only unmodified Fe2O3 nanoparticles are suitable for intended biosensing application in vitro (e.g. detection of viral nucleic acids) and the phase purification of this sample for this purpose is not necessary.
Keywords: Magnetic nanoparticles; iron oxide; gadolinium nanoparticles; silica coating
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Drbohlavova, J.; Hrdy, R.; Adam, V.; Kizek, R.; Schneeweiss, O.; Hubalek, J. Preparation and Properties of Various Magnetic Nanoparticles. Sensors 2009, 9, 2352-2362.
Drbohlavova J, Hrdy R, Adam V, Kizek R, Schneeweiss O, Hubalek J. Preparation and Properties of Various Magnetic Nanoparticles. Sensors. 2009; 9(4):2352-2362.
Drbohlavova, Jana; Hrdy, Radim; Adam, Vojtech; Kizek, Rene; Schneeweiss, Oldrich; Hubalek, Jaromir. 2009. "Preparation and Properties of Various Magnetic Nanoparticles." Sensors 9, no. 4: 2352-2362.