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Sensors 2008, 8(3), 1872-1878;
Abstract: An intensive temperature sensor based on a liquid-core optical fiber has been demonstrated for the measuring the temperature of the environment. The core of fiber is filled with a mixture of toluene and chloroform in order to make the refractive index of the liquid-core and the cladding of the fiber close. The experiment shows that a temperature sensitivity of about 5 dB/K and a tunable temperature range (from 20 °C to 60 °C) can be achieved. Based on the dielectric-clad liquid core fiber model, a simulation was carried out and the calculated results were in good accord with the experimental measurement.
Fiber-optical sensors have been developed in a lot of fields for many decades. They were widely used in the measurement for temperature, strain, voltage, electric current, vibration and so on [1-9]. Of all these sensors, intensity-modulated fiber-optic sensors usually combine the lowest cost with the simplest structure. In 1967, Kissinger and Frank first proposed the reflectometry intensity-modulated fiber-optic sensor. From then on, the intensity-modulated fiber-optics sensors have been applied in the measurement of all kinds of parameters such as temperature, displacement, pressure, refractive and so on [10-13]. Since 1960, a variety of fiber-optical sensors have been invented. Nowadays, optic-sensors can be classified depending on the different fiber materials or fiber structure, such as the traditional SMF, the birefringence fiber, the lanthanum doped fiber and the sub-wavelength fiber and microstructure optical fiber [14-17] in the recently years.
Liquid-core optical fiber (LCOF) is a different structure fiber which has been investigated since 1972 . A hollow fiber was filled with certain kinds of high index liquids to form the LCOF. In 1982, Kuribara and Takeda used hollow-core fibers filled with Kerr liquids for voltage measurements . In 1983, a distributed temperature measured technique based on time domain reflectometry techniques was presented . A measurement accuracy of 1°C with a spatial resolution of 1 m is attainable over a fiber length of 100m and consequently, a sensitivity of 2.3×10−2 dB/°C (0.54 percent °C−1) was observed. In 1991, Marten de Vries et al. first developed the liquid-core fiber temperature sensor , with a resolution of 0.2°C and a temperature range from 20°C to 185°C. However the sensitivity is low (about 7×10−3 dB/°C) at room temperature, which is hard to detect.
2. Experimental Section
2.1. LCOF sensor fabrication
In this paper, we present a new kind of temperature sensor based on the intensity-modulated principle. A hollow optical fiber is filled with a mixture of toluene and chloroform to form the LCOF. This kind of sensor has a high sensitivity in accurate temperature measurements and a tunable operational range, including room temperature, by simply changing the concentration of the two components. Practically, it also has an advantage of simplicity and low cost.
The sensor fiber is made of a hollow core silica fiber protected by a polyimide coating. The fiber can be commercially obtained with an inner core diameter of 250μm. In order to get a tight confinement ability, the diameter of the hollow core is stretched from 250μm to 50μm. Using a high pressure syringe system, the coated hollow fiber is filled with the liquid mixture, whose refractive index is a little higher than the silica clad. The low losses of the LCOF have been reported before .
2.2. Experiment setup
The configuration of the liquid-core optical fiber temperature sensor is shown in Figure 1. The light source is a tunable laser emitting continuous pulse of 1 mw power at a wavelength around 1550 nm. The laser is projected into the lead fiber of the sensor. The output of the sensor is directed through the lead fiber directly into the power meter. The two lead fibers are all inserted into the coating-stripped LCOF and the joint thus forms the sensor. The two lead fibers (A and C) are held at room temperature, whereas the LCOF part can be temperature-controlled. The temperature surrounding the LCOF is applied through a heated bath made by ourselves so that uniform temperature changes are insured.
Experimental results obtained from the setup are shown in Figure 2. In this experiment, mixtures with three different toluene concentrations which are separately 30%, 37.5%, 45% were applied. As the temperature is increased, the refractive index of the mixture decreased in a near linear fashion. When the refractive index approaches the index of the silica cladding, the propagation efficiency (η) decreases so that the intensity of the output decreases, too. Once the refractive index of the liquid core equal or smaller than the refractive of the silica cladding, no more light propagates through the fiber because the waveguide condition can not be met.
In Figure 2, when the concentration of the toluene is 30%, the linear sensitivity range is seen to be from 22°C to 26°C. The sensitivity of the sensor is about 5 dB/K. By adjusting the different concentration of the mixture, the different measurement range can be obtained. For the liquid with 37.5% toluene concentration, the range measured would be from 33°C to 37°C and also have the sensitivity 5 dB/K. When the liquid with 45% toluene concentration is used, the measured range from 41°C to 47°C can be obtained with the sensitivity 4dB/K−1. And similarly, in other operational range, the sensor's sensitivity should around 4-5dB/K. Such device is much sensitive, comparing to other temperature sensor as reported. 
3. Discussions and Conclusions
3.1. Simulation of the experiment
The mathematic model in our simulation is a cylindrical structure involving two regions: A liquid core with radius a and the infinite silica cladding. In our calculations, based on weakly-guiding theory, we ignore the length of the sensor fiber. Refractive indices of the liquid core (the mixture between toluene and chloroform) and the silica cladding are n2,n1, respectively. From the measured data , Sellmeier equations (1) were listed as follows at20°C.and the Sellmeier equation (2) for SiO2is:
By mixing the two liquids, we create a waveguide core of refractive index ranging from ntoluene to nchloroform. The relation between the refractive index of the mixed liquid nmxture and the concentration of toluene in the mixture ρ is unknown and needed to be measured. Generally, the refractive index of the mixed liquid nmxture as a function of the concentration of toluene in the mixture ρ can be expressed as the following equation (3) while considering the effect of temperature T:where dntoluene/dT=−5.273×10−4, dnchloroform/dt=−6.328×10−4are the thermal coefficients of the refractive indices.
We also should consider the effect of T to the coating material. Thus, the refractive index of the SiO2 should be expressed as follows:
From ,dnSiO2/dT∼−4×10−6, which shows that the thermal coefficient of the SiO2 is much more less than the liquids. Furthermore, in our experiment, the range of the changing temperature is limited.(about 40°C) For these two reasons, nsio2 can be seen as independent on temperature. The propagation efficiency (η) can be obtained with the equation (5).where N is the energy flow of light in the core and cladding region.
Because the index and the thermal coefficients of the mixture liquid are between those of toluene and chloroform, to simplify the process of simulation, we assume that f (ρ) = ρ; g(1−ρ) = 1−ρ, which under the assumption that the index of the mixture is linear with the concentration of the toluene. The simulation result is presented in the Figure 3. It shows that the experimental result accords with that of simulation well in the trend, and match the line well. It is should be noted that this assumption have little influence on the conclusions. In actual applications, the temperature dependence of refractive index at various concentrations should be measured.
In summary, a type of intensive based liquid core optical fiber temperature sensor has been proposed. The mixture of toluene and chloroform was pumped into the hollow fiber to form the liquid-core optical fiber. By adjusting the concentration of the liquid, different ranges of the temperature sensor can be realized. Experimentally, the sensor was found to have a sensitivity of 4 dB/K−1 to 5 dB/K−1 over the temperature range 20-60°C. Moreover the simple construction of this sensor shows an advantage in practical application.
This research was supported by the National Natural Science Foundation of China (No. 10574092); the National Basic Research Program “973” of China (No. 2007CB307000 and 2006CB806000);
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