Abstract: An electronic tongue for the qualitative analysis of aqueous solutions of salts hasbeen developed. The following set of electrodes was used: RuO2, Ag, and Cu in thick-filmtechnology and Au, Pb, Zn and Ni as small bars of the corresponding metal. The response ofthe designed “electronic tongue” was tested on a family of samples containing pure salt andcomplex mixtures. The electrodes were used as potentiometric un-specific sensors and thee.m.f. of each electrode in contact with a certain aqueous solution was used as input signalfor a PCA analysis. The study showed that the set of electrodes were capable to discriminatebetween aqueous solutions of salts basically by their different content in anions and cations(the anions SO42-, Cl-, PO4H2-, CO3H-, NO3- and cations Na+ and K+ were studied). In orderto better analyze the basis for the discrimination power shown by the electronic tongue, aquantitative analysis was also envisaged. A fair estimation of the concentrations of thedifferent ions in the solutions studied appeared to be possible using this electronic tonguedesign.Keywords:
Keywords: Electronic tongue; thick-film technology; metal electrodes; water discrimination.
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Gil, L.; Garcia-Breijo, E.; Ibañez, J.; Labrador, R.H.; Llobet, E.; Martínez-Máñez, R.; Soto, J. Electronic Tongue for Qualitative Analysis of Aqueous Solutions of Salts Using Thick-film Technology and Metal Electrodes. Sensors 2006, 6, 1128-1138.
Gil L, Garcia-Breijo E, Ibañez J, Labrador RH, Llobet E, Martínez-Máñez R, Soto J. Electronic Tongue for Qualitative Analysis of Aqueous Solutions of Salts Using Thick-film Technology and Metal Electrodes. Sensors. 2006; 6(9):1128-1138.
Gil, Luis; Garcia-Breijo, Eduardo; Ibañez, Javier; Labrador, Roberto H.; Llobet, Eduard; Martínez-Máñez, Ramón; Soto, Juan. 2006. "Electronic Tongue for Qualitative Analysis of Aqueous Solutions of Salts Using Thick-film Technology and Metal Electrodes." Sensors 6, no. 9: 1128-1138.