AbstractThis note describes a sequence converting an oxime-substituted pyrrolidine into a trisubstituted pyrrole structure. The synthetic route is based on a double chlorination of the pyrrolidine substrate followed by the base induced formation of both an imine and a nitrile oxide functionality. The latter reacts with an immobilized thiourea to yield an isothiocyanate which upon elimination generates the final pyrrole in an unprecedented cascade of events. View Full-Text
- Supplementary File 1:
Supplementary (ZIP, 235 KB)
Scifeed alert for new publicationsNever miss any articles matching your research from any publisher
- Get alerts for new papers matching your research
- Find out the new papers from selected authors
- Updated daily for 49'000+ journals and 6000+ publishers
- Define your Scifeed now
Baumann, M.; Baxendale, I.R. Ethyl 5-(4-Bromophenyl)-4-methyl-1H-pyrrole-2-carboxylate. Molbank 2017, 2017, M951.
Baumann M, Baxendale IR. Ethyl 5-(4-Bromophenyl)-4-methyl-1H-pyrrole-2-carboxylate. Molbank. 2017; 2017(3):M951.Chicago/Turabian Style
Baumann, Marcus; Baxendale, Ian R. 2017. "Ethyl 5-(4-Bromophenyl)-4-methyl-1H-pyrrole-2-carboxylate." Molbank 2017, no. 3: M951.
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.