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Molbank 2017, 2017(3), M950; doi:10.3390/M950

(OC-6-35-A)-Aquadicarbonylchlorido[2-(2-pyridyl)-1,8-naphthyridine-κ;2N1,N2]ruthenium(II) hexafluoridophosphate 2,2-Bipyridine

1
Institute of Environmental Radioactivity, Fukushima University, 1 Kanayagawa, Fukushima 960-1296, Japan
2
Cluster of Science and Engineering, Fukushima University, 1 Kanayagawa, Fukushima 960-1296, Japan
*
Author to whom correspondence should be addressed.
Received: 20 July 2017 / Revised: 1 August 2017 / Accepted: 1 August 2017 / Published: 3 August 2017
(This article belongs to the Section Structure Determination)
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Abstract

A dicarbonylruthenium(II) complex containing bidentate 2-(2-pyridyl)-1,8-naphthyridine, as well as monodentate aqua and chlorido ligands, were isolated and characterized using spectroscopic techniques and single crystal X-ray diffraction. These data indicate that geometrical isomerization occurs during the substitution reaction involving a superacid. Density functional theory (DFT) calculations were performed on the plausible geometrical isomers. The DFT-optimized structures and calculated infrared spectra suggest that the experimentally obtained structure is stable. View Full-Text
Keywords: ruthenium complex; carbonyl; naphthyridine; X-ray diffraction; hydrogen-bonding; computational chemistry; vibrational spectroscopy ruthenium complex; carbonyl; naphthyridine; X-ray diffraction; hydrogen-bonding; computational chemistry; vibrational spectroscopy
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Takase, T.; Abe, R.; Oyama, D. (OC-6-35-A)-Aquadicarbonylchlorido[2-(2-pyridyl)-1,8-naphthyridine-κ;2N1,N2]ruthenium(II) hexafluoridophosphate 2,2-Bipyridine. Molbank 2017, 2017, M950.

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