Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1'-(4,4'-(2- (1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-diyl) bis(oxy)bis(4,1-phenylene))diethanone

doi:10.3390/ijms9061000

This article is

freely available
re-usable

Int. J. Mol. Sci. 2008, 9(6), 1000-1007; doi:10.3390/ijms9061000

Article

Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1'-(4,4'-(2- (1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-diyl) bis(oxy)bis(4,1-phenylene))diethanone

Mustafa Er ¹ , Reşat Ustabaş ²^,* , Ufuk Çoruh ³ , Kemal Sancak ¹ and Ezequiel Vázquez-López ⁴

¹ Department of Chemistry Faculty of Arts and Sciences Karadeniz Teknik University, 61080-Trabzon, Turkey
² Department of Middle Education, Educational Faculty, Ondokuz Mayıs University 55200-Atakum-Samsun, Turkey
³ Department of Computer Education and Instructional Technology, Educational Faculty, Ondokuz Mayıs University 55200-Atakum-Samsun, Turkey
⁴ Departamento de Química Inorgánica, Facultade de Ciencias-Química, Universidade de Vigo, 36200-Vigo, Galicia, Spain

^* Author to whom correspondence should be addressed.

Received: 26 November 2007; in revised form: 15 April 2008 / Accepted: 18 April 2008 / Published: 13 June 2008

(This article belongs to the Section Physical Chemistry, Theoretical and Computational Chemistry)

Download PDF Full-Text [237 KB, uploaded 2 October 2008 12:05 CET]

Abstract: Tetraketone and tetraaldehyde derivatives 2a-d were synthesized via the reaction of ethene-1,1,2,2,-tetra-yl-tetramethylene tetrabromide (1) with hydroxyketone and aldehyde derivatives. The molecular structures were identifed by IR, ¹H-NMR, ¹³CNMR and MS analysis. The crystal structure of the title compound 2a, C₃₈H₃₆O₈, is reported. Its crystal data are: monoclinic, space group P 2(1)/n with cell dimensions of a= 9.0395(12) Å ,b= 12.6114(17) Å, c = 13.8166(18) Å, β= 95.875(3), V= 1566.8(4) Å³, F.W.= 620.67, ρ_calc =1.316 gcm³ for Z=2, μ=0.092 mm^-1

Keywords: 1; 3-bis(4-Acetylphenoxy)propan-2-ylidenepropane; 1; 3-di-ylbis(oxy)bis(4; 1- phenylene))diethanone; crystal structure; x-ray

Article Statistics

Click here to load and display the download statistics.

Cite This Article

MDPI and ACS Style

Er, M.; Ustabaş, R.; Çoruh, U.; Sancak, K.; Vázquez-López, E. Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1'-(4,4'-(2- (1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-diyl) bis(oxy)bis(4,1-phenylene))diethanone. Int. J. Mol. Sci. 2008, 9, 1000-1007.

AMA Style

Er M., Ustabaş R., Çoruh U., Sancak K., Vázquez-López E. Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1'-(4,4'-(2- (1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-diyl) bis(oxy)bis(4,1-phenylene))diethanone. International Journal of Molecular Sciences. 2008; 9(6):1000-1007.

Chicago/Turabian Style

Er, Mustafa; Ustabaş, Reşat; Çoruh, Ufuk; Sancak, Kemal; Vázquez-López, Ezequiel. 2008. "Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1'-(4,4'-(2- (1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-diyl) bis(oxy)bis(4,1-phenylene))diethanone." Int. J. Mol. Sci. 9, no. 6: 1000-1007.

Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI Publishing, Basel, Switzerland RSS E-Mail Table of Contents Alert