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Int. J. Mol. Sci. 2016, 17(9), 1452; doi:10.3390/ijms17091452

Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids

1
Department of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany
2
Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Strasse 40, 01187 Dresden, Germany
*
Author to whom correspondence should be addressed.
Academic Editors: Andreas Taubert and Peter Hesemann
Received: 5 July 2016 / Revised: 19 August 2016 / Accepted: 23 August 2016 / Published: 1 September 2016
(This article belongs to the Special Issue Ionic Liquids 2016 and Selected Papers from ILMAT III)
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Abstract

Ionic liquids (ILs) have been proven to be valuable reaction media for the synthesis of inorganic materials among an abundance of other applications in different fields of chemistry. Up to now, the syntheses have remained mostly “black boxes”; and researchers have to resort to trial-and-error in order to establish a new synthetic route to a specific compound. This review comprises decisive reaction parameters and techniques for the directed synthesis of polyions of heavy main-group elements (fourth period and beyond) in ILs. Several families of compounds are presented ranging from polyhalides over carbonyl complexes and selenidostannates to homo and heteropolycations. View Full-Text
Keywords: amines; ionic liquids; ionothermal; main-group elements; modifications; polyanions; polycations; starting materials; synthesis parameters; vapor pressure amines; ionic liquids; ionothermal; main-group elements; modifications; polyanions; polycations; starting materials; synthesis parameters; vapor pressure
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Groh, M.F.; Wolff, A.; Grasser, M.A.; Ruck, M. Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids. Int. J. Mol. Sci. 2016, 17, 1452.

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