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Fluorescence Studies of Selected 2-Alkylaminopyrimidines
AbstractThe reactions of 2-chloropyrimidine with methylamine, ethylamine and piperidine gave the corresponding 2-N-methylamino-, 2-N-ethylamino- and 2N- piperidinopyrimidines, respectively. The fluorescence properties of these alkylamino derivatives in chloroform, ethyl acetate, carbon tetrachloride, acetone, ether, ethanol and methanol were studied. All the alkylamino derivatives showed the highest fluorescence intensity in polar protic solvents; thus 2-N-methylaminopyrimidine (highest fluorescence intensity at 377 nm when excited at 282 nm) and 2-N-ethylaminopyrimidine (highest fluorescence intensity at 375 nm, when excited at 286 nm) showed the highest fluorescence in methanol. In ethanol, 2-N-piperidinopyrimidine showed a fluorescence peak at 403 nm when excited at 360 nm and in chloroform it fluoresced at 392 nm when excited at 356 nm.
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Abdullah, Z.; Tahir, N.M.; Abas, M.R.; Aiyub, Z.; Low, B.K. Fluorescence Studies of Selected 2-Alkylaminopyrimidines. Molecules 2004, 9, 520-526.View more citation formats
Abdullah Z, Tahir NM, Abas MR, Aiyub Z, Low BK. Fluorescence Studies of Selected 2-Alkylaminopyrimidines. Molecules. 2004; 9(7):520-526.Chicago/Turabian Style
Abdullah, Z.; Tahir, N. M.; Abas, M. R.; Aiyub, Z.; Low, B. K. 2004. "Fluorescence Studies of Selected 2-Alkylaminopyrimidines." Molecules 9, no. 7: 520-526.