Next Article in Journal
Electron-Induced (EI) Mass Fragmentation is Directed by Intra- molecular H-Bonding in Two Isomeric Benzodipyran Systems
Previous Article in Journal
Synthesis of Novel Azo Schiff Bases and Their Antibacterial and Antifungal Activities
Molecules 2004, 9(10), 825-829; doi:10.3390/91000825
Article

Synthesis and Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Oxidant

* ,  and
Received: 28 June 2004 / Revised: 11 June 2004 / Accepted: 15 June 2004 / Published: 30 September 2004
Download PDF [170 KB, uploaded 18 June 2014]

Abstract

N-Methylbenzylammonium fluorochromate(VI) (MBAFC) is easily synthesized by addition of N-methylbenzylamine to an aqueous solution of CrO3 and HF. MBAFC shows selectivity in the oxidation of aryl alcohols to their corresponding aldehydes and ketones under mild conditions. The durability, ease of work up and efficiency of MBAFC are considerably increased upon its absorption on silica gel.
Keywords: N-Methylbenzylammonium fluorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols. N-Methylbenzylammonium fluorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols.
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote
MDPI and ACS Style

Kassaee, M.Z.; Sayyed-Alangi, S.Z.; Sajjadi-Ghotbabadi, H. Synthesis and Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Oxidant. Molecules 2004, 9, 825-829.

View more citation formats

Related Articles

Article Metrics

Comments

Citing Articles

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert