Next Article in Journal
Electron-Induced (EI) Mass Fragmentation is Directed by Intra- molecular H-Bonding in Two Isomeric Benzodipyran Systems
Previous Article in Journal
Synthesis of Novel Azo Schiff Bases and Their Antibacterial and Antifungal Activities
Article Menu

Export Article

Open AccessArticle
Molecules 2004, 9(10), 825-829; doi:10.3390/91000825

Synthesis and Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Oxidant

Department of Chemistry, Tarbiat Modarres University, P.O. Box 14155-4838, Tehran, Iran
*
Author to whom correspondence should be addressed.
Received: 28 June 2004 / Revised: 11 June 2004 / Accepted: 15 June 2004 / Published: 30 September 2004
View Full-Text   |   Download PDF [170 KB, uploaded 18 June 2014]   |  

Abstract

N-Methylbenzylammonium fluorochromate(VI) (MBAFC) is easily synthesized by addition of N-methylbenzylamine to an aqueous solution of CrO3 and HF. MBAFC shows selectivity in the oxidation of aryl alcohols to their corresponding aldehydes and ketones under mild conditions. The durability, ease of work up and efficiency of MBAFC are considerably increased upon its absorption on silica gel.
Keywords: N-Methylbenzylammonium fluorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols. N-Methylbenzylammonium fluorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols.
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Kassaee, M.Z.; Sayyed-Alangi, S.Z.; Sajjadi-Ghotbabadi, H. Synthesis and Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Oxidant. Molecules 2004, 9, 825-829.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top