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Molecules 2004, 9(1), 22-28; doi:10.3390/90100022
Article

Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers

*  and
Department of Chemistry, Firat University, Faculty of Science and Arts, 23169, Elazig, Turkey
* Author to whom correspondence should be addressed.
Received: 25 September 2003 / Revised: 9 January 2004 / Accepted: 19 January 2004 / Published: 31 January 2004
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Abstract

Heteroaryl substituted allyl and homoallyl alcohols were synthesised with two different method. Synthesis of bis-allyl ethers and homoallyl ethers were carried out via reaction of allyl bromide with allyl alcohols and homoallyl alcohols, respectively. [2.3]-Wittig Rearrangement reactions of heteroaryl substituted bis-allyl ethers were investigated using GC/MS techniques. In these reactions two unexpected products were isolated in high yield.
Keywords: Nozaki-Hiyama reaction; Organochromium reagents; Hetero- aromatic aldehydes Nozaki-Hiyama reaction; Organochromium reagents; Hetero- aromatic aldehydes
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Servi, S.; Topaloglu, C. Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers. Molecules 2004, 9, 22-28.

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