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Molecules 2003, 8(1), 74-84; doi:10.3390/80100074
Article

A Method for Synthesizing Partially Substituted Cucurbit[n]uril

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Received: 1 January 2003; Published: 31 January 2003
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Abstract: A novel approach to cucurbituril synthesis is described where partial substitution is introduced into cucurbit[n]uril. The identification of homologues (and their substitution) in reaction mixtures is achieved by a combination of ESMS and the use of the molecular probes (guests) 1,4-dioxane and 1,9-octanediamine. A unique symmetrical hexamethylcucurbit[3,3]uril, the major product, was isolated and characterized.
Keywords: Macrocycles; molecular binding; partially substituted Macrocycles; molecular binding; partially substituted
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Day, A.I.; Arnold, A.P.; Blanch, R.J. A Method for Synthesizing Partially Substituted Cucurbit[n]uril. Molecules 2003, 8, 74-84.

AMA Style

Day AI, Arnold AP, Blanch RJ. A Method for Synthesizing Partially Substituted Cucurbit[n]uril. Molecules. 2003; 8(1):74-84.

Chicago/Turabian Style

Day, Anthony I.; Arnold, Alan P.; Blanch, Rodney J. 2003. "A Method for Synthesizing Partially Substituted Cucurbit[n]uril." Molecules 8, no. 1: 74-84.


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