Next Article in Journal
Regioselective Protection of the 4-Hydroxyl of 3,4-Dihydroxy-benzaldehyde
Previous Article in Journal
Synthesis and Biological Activity of 3-(2-Furanyl)-6-Aryl-1,2,4-Triazolo[3,4-b]-1,3,4 –Thiadiazoles
Molecules 2002, 7(9), 690-696; doi:10.3390/70900690
Article

Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

1, 1, 1, 1, 2, 2, 2, 3 and 1,3,*
1 Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco 2 CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France 3 Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
* Author to whom correspondence should be addressed.
Received: 13 May 2002 / Revised: 9 September 2002 / Accepted: 10 September 2002 / Published: 30 September 2002
View Full-Text   |   Download PDF [366 KB, uploaded 18 June 2014]   |  

Abstract

The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.
Keywords: Structure; tripod; pyrazole; tridentate; flexible ligand Structure; tripod; pyrazole; tridentate; flexible ligand
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
SciFeed

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote |
RIS
MDPI and ACS Style

Daoudi, M.; Larbi, N.B.; Benjelloun, D.; Kerbal, A.; Launay, J.P.; Bonvoisin, J.; Jaud, J.; Mimouni, M.; Ben-Hadda, T. Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline. Molecules 2002, 7, 690-696.

View more citation formats

Related Articles

Article Metrics

For more information on the journal, click here

Comments

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert