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Molecules 2002, 7(9), 690-696; doi:10.3390/70900690

Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

1
Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco
2
CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France
3
Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
*
Author to whom correspondence should be addressed.
Received: 13 May 2002 / Revised: 9 September 2002 / Accepted: 10 September 2002 / Published: 30 September 2002
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Abstract

The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.
Keywords: Structure; tripod; pyrazole; tridentate; flexible ligand Structure; tripod; pyrazole; tridentate; flexible ligand
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Daoudi, M.; Larbi, N.B.; Benjelloun, D.; Kerbal, A.; Launay, J.P.; Bonvoisin, J.; Jaud, J.; Mimouni, M.; Ben-Hadda, T. Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline. Molecules 2002, 7, 690-696.

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