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Molecules 2002, 7(9), 690-696; doi:10.3390/70900690
Article

Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

1, 1, 1, 1, 2, 2, 2, 3 and 1,3,*
1 Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco 2 CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France 3 Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
* Author to whom correspondence should be addressed.
Received: 13 May 2002 / Revised: 9 September 2002 / Accepted: 10 September 2002 / Published: 30 September 2002
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Abstract

The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.
Keywords: Structure; tripod; pyrazole; tridentate; flexible ligand Structure; tripod; pyrazole; tridentate; flexible ligand
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Daoudi, M.; Larbi, N.B.; Benjelloun, D.; Kerbal, A.; Launay, J.P.; Bonvoisin, J.; Jaud, J.; Mimouni, M.; Ben-Hadda, T. Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline. Molecules 2002, 7, 690-696.

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