Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

doi:10.3390/70900690

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Molecules 2002, 7(9), 690-696; doi:10.3390/70900690

Article

Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

Maria Daoudi¹, Najib Ben Larbi¹, Driss Benjelloun¹, Abdelali Kerbal¹, Jean Pierre Launay², Jacques Bonvoisin², Joël Jaud², Mostafa Mimouni³ and Taibi Ben-Hadda^1,3,*

¹ Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco ² CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France ³ Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco

* Author to whom correspondence should be addressed.

Received: 13 May 2002; in revised form: 9 September 2002 / Accepted: 10 September 2002 / Published: 30 September 2002

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Abstract: The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.

Keywords: Structure; tripod; pyrazole; tridentate; flexible ligand

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MDPI and ACS Style

Daoudi, M.; Larbi, N.B.; Benjelloun, D.; Kerbal, A.; Launay, J.P.; Bonvoisin, J.; Jaud, J.; Mimouni, M.; Ben-Hadda, T. Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline. Molecules 2002, 7, 690-696.

AMA Style

Daoudi M, Larbi NB, Benjelloun D, Kerbal A, Launay JP, Bonvoisin J, Jaud J, Mimouni M, Ben-Hadda T. Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline. Molecules. 2002; 7(9):690-696.

Chicago/Turabian Style

Daoudi, Maria; Larbi, Najib B.; Benjelloun, Driss; Kerbal, Abdelali; Launay, Jean P.; Bonvoisin, Jacques; Jaud, Joël; Mimouni, Mostafa; Ben-Hadda, Taibi. 2002. "Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline." Molecules 7, no. 9: 690-696.

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