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Synthesis of Substituted 2-Pyridyl-4-phenylquinolines
Department of Physical and Chemical Methodologies for Engineering, Engineering Faculty, University of Catania, V.le Andrea Doria 6, I-95125 Catania, Italy
* Author to whom correspondence should be addressed.
Received: 21 June 2002; in revised form: 2 August 2002 / Accepted: 3 August 2003 / Published: 31 August 2002
Abstract: The acid-catalyzed condensation of o-aminobenzophenones with aromatic acetyl derivatives, in a basic methanol/tetrahydrofuran medium, has been used to prepare a series of substituted 2-pyridyl-4-phenylquinolines. Derivatives having two aza binding sites can act as asymmetric bidendate ligands to complex transition metals such as ruthenium, osmium or iridium. All the compounds were characterized by elemental analysis, Ei or FAB (+) MS, 1H- and 13C-NMR spectroscopies. Complete assignments of the 1H spectra were accomplished by using a combination of one- and two-dimensional NMR techniques.
Keywords: Quinoline derivatives; asymmetric bidentate aza-ligands; 2D-NMR
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MDPI and ACS Style
Mamo, A.; Nicoletti, S.; Tat, N.C. Synthesis of Substituted 2-Pyridyl-4-phenylquinolines. Molecules 2002, 7, 618-627.
Mamo A, Nicoletti S, Tat NC. Synthesis of Substituted 2-Pyridyl-4-phenylquinolines. Molecules. 2002; 7(8):618-627.
Mamo, Antonino; Nicoletti, Salvatore; Tat, N. C. 2002. "Synthesis of Substituted 2-Pyridyl-4-phenylquinolines." Molecules 7, no. 8: 618-627.