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Molecules 2002, 7(8), 601-617; doi:10.3390/70800601
Article

Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates

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Received: 16 May 2002; in revised form: 13 August 2002 / Accepted: 24 August 2002 / Published: 31 August 2002
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Abstract: The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.
Keywords: Alkylation reagents; SN2 substitution reactions; steric hindrance; sulfonic esters; sulfur-oxygen bond cleavage. Alkylation reagents; SN2 substitution reactions; steric hindrance; sulfonic esters; sulfur-oxygen bond cleavage.
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Netscher, T.; Bohrer, P. Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates. Molecules 2002, 7, 601-617.

AMA Style

Netscher T, Bohrer P. Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates. Molecules. 2002; 7(8):601-617.

Chicago/Turabian Style

Netscher, Thomas; Bohrer, Patrick. 2002. "Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates." Molecules 7, no. 8: 601-617.


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