Molecules 2002, 7(8), 601-617; doi:10.3390/70800601
Article

Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates

Research and Development, Roche Vitamins Ltd, CH-4070 Basel, Switzerland
* Author to whom correspondence should be addressed.
Received: 16 May 2002; in revised form: 13 August 2002 / Accepted: 24 August 2002 / Published: 31 August 2002
PDF Full-text Download PDF Full-Text [371 KB, uploaded 3 October 2008 10:29 CEST]
Abstract: The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.
Keywords: Alkylation reagents; SN2 substitution reactions; steric hindrance; sulfonic esters; sulfur-oxygen bond cleavage.

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Netscher, T.; Bohrer, P. Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates. Molecules 2002, 7, 601-617.

AMA Style

Netscher T, Bohrer P. Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates. Molecules. 2002; 7(8):601-617.

Chicago/Turabian Style

Netscher, Thomas; Bohrer, Patrick. 2002. "Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates." Molecules 7, no. 8: 601-617.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert