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Molecules 2002, 7(7), 549-553; doi:10.3390/70700549

Synthesis and Structure of the Cadmium (II) Complex: [Cd(C5H5N)2(S2CO-n-C4H9)2]

1,2, 1,* , 1 and 3
1 Department of Chemistry, South China Normal University, Guangzhou 510631, P.R. China 2 Department of Foundation, Zhongkai Agrotechnical College, Guangzhou 510230, P.R. China 3 Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300, P.R. China
* Author to whom correspondence should be addressed.
Received: 9 February 2002 / Revised: 30 July 2002 / Accepted: 31 July 2002 / Published: 31 July 2002
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The [Cd(C5H5N)2(S2CO-n-C4H9)2] adduct of pyridine with [Cd(S2CO-n-C4H9)2]n was synthesized and characterized by IR, elemental analysis,1H-NMR and X-ray diffraction analysis. The crystasl belong to the monoclinic system, space group P2(1)/c with Z=2. Cell dimensions are a=1.1094(12), b=0.6152(6), c=1.7985(19) nm, • =96.148(2)°, V=1.2204(2)nm3. The structure was refined to R=0.0246 and wR=0.0645 for 2624 reflections with I>2•(I). The complex has a centrosymmetric molecule structure.
Keywords: n-Butylxanthate; cadmium (II) complex; pyridine; crystal structure n-Butylxanthate; cadmium (II) complex; pyridine; crystal structure
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Jiang, X.H.; Zhang, W.G.; Zhong, Y.; Wang, S.L. Synthesis and Structure of the Cadmium (II) Complex: [Cd(C5H5N)2(S2CO-n-C4H9)2]. Molecules 2002, 7, 549-553.

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