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Molecules 2002, 7(6), 475-486; doi:10.3390/70600475
Article

Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions

* ,  and
Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Av. Bandeirantes 3900, 14040-901 – Ribeirão Preto – SP, Brazil
* Author to whom correspondence should be addressed.
Received: 17 August 2001 / Revised: 28 June 2002 / Accepted: 28 June 2002 / Published: 30 June 2002
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Abstract

In this paper we describe the synthesis of a γ,δ-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to accomplish a synthesis that would be otherwise straightforward. Suggestions to account for the results are given.
Keywords: Diels-Alder adducts; Intramolecular interactions; 1; 4-Diols oxidation; Cyclic phosphite Diels-Alder adducts; Intramolecular interactions; 1; 4-Diols oxidation; Cyclic phosphite
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Constantino, M.G.; De Souza, A.X.; Da Silva, G.V.J. Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions. Molecules 2002, 7, 475-486.

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