Molecules 2002, 7(6), 475-486; doi:10.3390/70600475
Article

Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions

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Received: 17 August 2001; in revised form: 28 June 2002 / Accepted: 28 June 2002 / Published: 30 June 2002
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: In this paper we describe the synthesis of a γ,δ-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to accomplish a synthesis that would be otherwise straightforward. Suggestions to account for the results are given.
Keywords: Diels-Alder adducts; Intramolecular interactions; 1; 4-Diols oxidation; Cyclic phosphite
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MDPI and ACS Style

Constantino, M.G.; De Souza, A.X.; Da Silva, G.V.J. Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions. Molecules 2002, 7, 475-486.

AMA Style

Constantino MG, De Souza AX, Da Silva GVJ. Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions. Molecules. 2002; 7(6):475-486.

Chicago/Turabian Style

Constantino, Mauricio G.; De Souza, Altamiro X.; Da Silva, Gil V.J. 2002. "Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions." Molecules 7, no. 6: 475-486.

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