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Molecules 2001, 6(9), 777-783; doi:10.3390/60900777
Article

Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II)

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Received: 5 December 2000; in revised form: 26 August 2001 / Accepted: 27 August 2001 / Published: 31 August 2001
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Abstract: The single crystal structure of cis-dichlorobis(triphenyphosphite) platinum(II), [PtCl2(P(OPh)3)2] has been determined. This complex crystallises in the orthorhombic space group, P212121 with cell constant, a=10.4135(13), b=14.0635(16), c=23.505(3) Ǻ and v=3448.3(7) Ǻ 3. The Pt-Cl1 and Pt-Cl2 distances are 2.3390(10) Ǻ and 2.3256 Ǻ, which are longer than Pt-P1 and Pt-P2 with 2.1985(12) Ǻ and 2.1998(10) Ǻ respectively. These data together with bond angles suggest a distorted square planar geometry for this complex with two chlorine ligands in a cis configuration.
Keywords: Crystal structure; Molecular structure; Triphenylphosphite ligands; Platinum complex Crystal structure; Molecular structure; Triphenylphosphite ligands; Platinum complex
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Sabounchei, S.J.; Naghipour, A. Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II). Molecules 2001, 6, 777-783.

AMA Style

Sabounchei SJ, Naghipour A. Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II). Molecules. 2001; 6(9):777-783.

Chicago/Turabian Style

Sabounchei, Seyyed J.; Naghipour, Ali. 2001. "Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II)." Molecules 6, no. 9: 777-783.


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