One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant

doi:10.3390/61100869

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Molecules 2001, 6(11), 869-874; doi:10.3390/61100869

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One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant

Nicolas Obeid and Lech Skulski *

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, Banacha 1, PL 02-097 Warsaw, Poland

* Author to whom correspondence should be addressed.

Received: 27 September 2001; in revised form: 11 October 2001 / Accepted: 12 October 2001 / Published: 31 October 2001

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Abstract: Ten representative (dichloroiodo)arenes, ArICl₂, were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I₂/CrO₃/AcOH/Ac₂O/conc. H₂SO₄, followed by the addition of conc. hydrochloric acid, used as the source of chlorine; ArICl₂ are useful in organic synthesis as mild and selective chlorinating and/or oxidizing agents.

Keywords: (dichloroiodo)arenes; arenes; diiodine; chromium(VI) oxide as oxidant

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MDPI and ACS Style

Obeid, N.; Skulski, L. One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant. Molecules 2001, 6, 869-874.

AMA Style

Obeid N., Skulski L. One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant. Molecules. 2001; 6(11):869-874.

Chicago/Turabian Style

Obeid, Nicolas; Skulski, Lech. 2001. "One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant." Molecules 6, no. 11: 869-874.

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